1964
DOI: 10.1002/cber.19640970635
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Synthese von 6a‐Thia‐thiophthenen aus Trithionen

Abstract: Eine ergiebige Synthese von 6a‐Thia‐thiophthenen (V), ausgehend von Trithionen und aromatischen Cyanmethylketonen, wird beschrieben; einige chemische Argumente zur Konstitution werden mitgeteilt.

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Cited by 33 publications
(2 citation statements)
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“…α-Haloketones may undergo two competitive reactions with sodium or potassium cyanide. Nucleophilic addition and intra-molecular substitution lead to 2-cyanooxiranes 235 [ 465 , 466 , 467 , 468 , 469 , 470 , 471 , 472 , 473 , 474 , 475 , 476 , 477 , 478 , 479 ] ( Scheme 70 ).…”
Section: Reactions Of α-Haloketones With Carbon Nucleophilesmentioning
confidence: 99%
“…α-Haloketones may undergo two competitive reactions with sodium or potassium cyanide. Nucleophilic addition and intra-molecular substitution lead to 2-cyanooxiranes 235 [ 465 , 466 , 467 , 468 , 469 , 470 , 471 , 472 , 473 , 474 , 475 , 476 , 477 , 478 , 479 ] ( Scheme 70 ).…”
Section: Reactions Of α-Haloketones With Carbon Nucleophilesmentioning
confidence: 99%
“…α-Haloketones may undergo two competitive reactions with sodium or potassium cyanide. Nucleophilic addition and intramolecular substitution lead to 2-cyanooxiranes 235 [465][466][467][468][469][470][471][472][473][474][475][476][477][478][479] (Scheme 70).…”
Section: Reactions Of α-Haloketones With Carbon Nucleophilesmentioning
confidence: 99%