In the past seven years, dual Z-scheme heterojunctions
evolved
as favorable approaches for enhanced charge carrier separation through
direct or indirect charge transfer transportation mechanisms. The
dynamics of the charge transfer is the major strategy for understanding
their photoactivity and stability through the formation of distinctive
redox centers. The understanding of currently recognized principles
for successful fabrication and classification in different energy
and pollution remediation strategies is discussed, and a universal
charge transfer-type-based classification of dual Z-schemes that can
be adopted for Z-scheme and S-scheme heterojunctions is proposed.
Methods used for determining the charge transfer as proof of dual
Z-scheme existence are outlined. Most importantly, a new macroscopic
N-scheme and a triple Z-scheme that can also be adopted as triple
S-scheme heterostructures composed of four semiconductors are proposed
for generating both oxidatively and reductively empowered systems.
The proposed systems are expected to possess properties that enable
them to harvest solar light to drive important chemical reactions
for different applications.