Increasing attention has recently been given to studying the effect of surfactants added to solution for enhancing absorption. Most researchers relate the enhancement of mass transfer in absorption to the fact that, near the interface, a convection boundary is formed under the action of interfacial tension gradients. Various mechanisms of the emergence of interfacial tension nonuniformities have been discussed. Attempts have also been made to study the stability and perform mathematical modeling of the transfer processes in absorption by surfactant-containing solutions [1][2][3]. For this purpose, it is necessary to have data on the dependence of the interfacial tension on the determining parameters under absorption conditions, in particular, in the absorbers of heat pumps and refrigerating machines. In this case, one should consider the liquid solution-vapor two-phase system in which the interface is in equilibrium at constant vapor pressure, which is one of the features of the operation of the absorber in a heat pump or a refrigerating machine. A system in which the liquid phase is an aqueous lithium bromide solution and the gas phase is water vapor is most often analyzed. This system is also typically used in experimental investigations, including those of the effect of surfactants (usually, various alcohols) on the absorption intensity.The studies of the heat and mass transfer in the absorption of water vapor by an aqueous lithium bromide solution generally use data on surface tension, i.e., data obtained for a system in which the gas phase is air, whereas, in the case under consideration, the gas phase is water vapor and the interfacial tension should be considered (according to the accepted terminology [4]). Data on the interfacial tension in the aqueous lithium bromide solution-water vapor system in equilibrium at constant vapor pressure are unavailable. To answer the question of how available data on surface tension should be used, let us initially consider an aqueous lithium bromide solution without surfactant.Data on the surface tension of aqueous lithium bromide solutions without surfactant [5][6][7] and with various surfactants [2, 7-9] are available in the literature. These data are usually presented as tables or plots describing the dependence of the surface tension on two independent variables: the lithium bromide concentration in solution (or water) and temperature. The vapor partial pressure in the gas phase is not presented. These data were obtained for the system in equilibrium; therefore, from each pair of values of the temperature T and the concentration C , one can calculate the vapor partial pressure P from expressions P = P ( C , T ) describing the equilibrium state. Table 1 gives the vapor partial pressure values calculated from the published equilibrium expressions [10] and also presents the surface tension data σ [7].In the absorption during the operation of a heat pump, the gas phase is pure water vapor; therefore, the total pressure of the vapor coincides with its partial pressure and...