2023
DOI: 10.1002/chem.202203971
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Surface‐Stabilized CsPbI3 Nanocrystals with Tailored Organic Polymer Ligand Binding

Abstract: Perovskite nanocrystals (NCs) exhibit attractive photophysical properties by combining the excellent optoelectronic properties of bulk perovskites with the strong quantum confinement effect at the nanoscale. However, CsPbI 3 NCs easily transform into a non-perovskite phase because of the ionic lattice and dynamic ligand binding. Herein, stable black-phase CsPbI 3 NCs capped with a new organic ligand, HO-PS-N 3 (HOPS), which consists of a polystyrene segment with hydroxyl and azide end groups, are reported. Thi… Show more

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