Surface Properties and In Vitro Corrosion Studies of Blasted and Thermally Treated Ti6Al4V Alloy for Bioimplant Applications

Abstract

The biomedical Ti6Al4V alloy was thermally treated under sandblasting and mirror finish surface preparation conditions. The surface morphology, structure, roughness, wettability, and energy were characterized. Microhardness and in vitro corrosion studies were carried out. X-ray diffraction results showed a formation of rutile TiO2 phase for thermally treated samples under different pretreated conditions. The thermally oxidized samples exhibited an increase in microhardness compared to the untreated mirror finish and sandblasted samples by 22 and 33%, respectively. The wettability study revealed enhanced hydrophilicity of blasted and thermally treated samples. The surface energy of the thermal treatment samples increased by 26 and 32.6% for mirror surface and blasted preconditions, respectively. The acquired in vitro corrosion results using potentiodynamic polarization measurement and electrochemical impedance spectroscopy confirmed the surface protective performance against corrosion in Hank’s medium. The enhanced surface characteristics and corrosion protection of treated Ti6Al4V alloy give it potential for bio-implant applications.

Research progress of metal biomaterials with potential applications as cardiovascular stents and their surface treatment methods to improve biocompatibility

“…Many surface treatment methods currently exist, including chemical methods [ 68 ] and physical methods [ 69 ]. Physical methods consist of milling [ 70 ], laser [ [71] , [72] , [73] ], sandblasting [ 74 , 75 ], and electrical discharge machining (EDM) [ 76 , 77 ], while chemical methods include acid [ 78 ] and alkali treatment [ 79 , 80 ], nitriding [ 81 , 82 ], and plasma treatment [ 83 , 84 ]. In addition, some electrochemical methods are available, such as electropolishing [ 85 , 86 ], electrolytic polishing [ 87 , 88 ], anodic oxidation [ 89 , 90 ], and micro-arc oxidation (MAO, also known as plasma electrolytic oxidation) [ 80 , 91 ].…”