“…This suggests that the low binding energy peak at 203.1 eV can be attributed to the metallic Nb instead of oxidized state of Nb and that the binding energy value is shifted to a higher value from the value of the bulk Nb metal. The same phenomenon was observed in segregation study of Nb on an Inconel 718 (100) single crystal (austenitic NiCrbased superalloy), where metallic Nb was found at 203.4 eV, and concluded to originate from possible formation of a Nb intermetallic surface phase [41]. Such core level shifts (CLSs) for metallic Nb in intermetallic compounds have also been reported for Ni 3 Nb model system [42], NbeZr interface [43], Nb in TiAl alloy [44], and Cr 2 Nb [45].…”