“…Resonant gravimetric detection − is more amenable toward miniaturization and integration into the equipment by using little power while still maintaining the required sensitivity and selectivity . Some gravimetric detection methods have proven to be useful in many applications with numerous methods developed including quartz crystal microbalances (QCM), film bulk acoustic resonators (FBARs), surface acoustic wave (SAW) sensors, − micro- and nanocantilevers, − and capacitive micromachined ultrasonic transducers (CMUTs). ,− QCM is a low-cost, real-time measurement technique with the limit of quantification (LOQ)the lowest concentration of the analyte in a sample that can be quantifiedranging from 0.001 to 0.5 Hz/ppm with signal-to-noise (SNR) ranging from 1 to 300. Unlike QCMs, FBARs use shear wave excitation on bulk machined freestanding resonance structures, such as microbridges, microplates, and microcantilevers with thin piezoelectric films.…”
A capacitive
micromachined ultrasonic transducer (CMUT)-based sensor modified with
methylated poly(ethylenimine) (mPEI) was designed and tested for the
detection of two acidic gases: carbon dioxide (CO2) and
sulfur dioxide (SO2). Combined gas sensing and Fourier
transform infrared spectroscopy of the adsorbed products allowed to
simultaneously and in situ determine the types and
strength of the molecular interactions responsible for sensing. For
CO2, the limit of detection was calculated to be 0.011
CO2 vol % and the limit of quantification was calculated
to be 0.033%. For SO2, the limit of detection was calculated
as 0.232 SO2 vol % and the limit of quantification was
0.704%. The sensing system exhibited a linear response at lower concentrations
for CO2 and linear response for all the tested concentrations
of SO2. In situ IR and ex situ Raman showed that CO2 was observed to undergo weak molecular
coordination with mPEI while SO2 bound strongly and irreversibly
degraded the thin mPEI films.
“…Resonant gravimetric detection − is more amenable toward miniaturization and integration into the equipment by using little power while still maintaining the required sensitivity and selectivity . Some gravimetric detection methods have proven to be useful in many applications with numerous methods developed including quartz crystal microbalances (QCM), film bulk acoustic resonators (FBARs), surface acoustic wave (SAW) sensors, − micro- and nanocantilevers, − and capacitive micromachined ultrasonic transducers (CMUTs). ,− QCM is a low-cost, real-time measurement technique with the limit of quantification (LOQ)the lowest concentration of the analyte in a sample that can be quantifiedranging from 0.001 to 0.5 Hz/ppm with signal-to-noise (SNR) ranging from 1 to 300. Unlike QCMs, FBARs use shear wave excitation on bulk machined freestanding resonance structures, such as microbridges, microplates, and microcantilevers with thin piezoelectric films.…”
A capacitive
micromachined ultrasonic transducer (CMUT)-based sensor modified with
methylated poly(ethylenimine) (mPEI) was designed and tested for the
detection of two acidic gases: carbon dioxide (CO2) and
sulfur dioxide (SO2). Combined gas sensing and Fourier
transform infrared spectroscopy of the adsorbed products allowed to
simultaneously and in situ determine the types and
strength of the molecular interactions responsible for sensing. For
CO2, the limit of detection was calculated to be 0.011
CO2 vol % and the limit of quantification was calculated
to be 0.033%. For SO2, the limit of detection was calculated
as 0.232 SO2 vol % and the limit of quantification was
0.704%. The sensing system exhibited a linear response at lower concentrations
for CO2 and linear response for all the tested concentrations
of SO2. In situ IR and ex situ Raman showed that CO2 was observed to undergo weak molecular
coordination with mPEI while SO2 bound strongly and irreversibly
degraded the thin mPEI films.
“…Currently, predominant commercial solutions include surface acoustic wave (SAW) resonators and thin-film bulk acoustic wave resonators (FBARs), which are known for their high performance and cost-effectiveness [1,2]. However, conventional SAW devices, fabricated using bulk lithium niobate (LiNbO 3 ) or lithium tantalate (LiTaO 3 ), encounter challenges in achieving ultra-high frequencies because of limitations on electrode width and the relatively low phase velocity (v) of acoustic modes propagating through the piezoelectric substrates [3,4]. While the resonance frequency (f s ) of FBARs is primarily determined by their thickness, allowing for an increase in f s by merely reducing the thickness of the electrode and piezoelectric layer, this reduction in thickness inevitably leads to compromised deposition quality and increased ohmic loss [5,6].…”
The piezoelectric thin film composed of single-crystal lithium niobate (LiNbO3) exhibits a remarkably high electromechanical coupling coefficient and minimal intrinsic losses, making it an optimal material for fabricating bulk acoustic wave resonators. However, contemporary first-order antisymmetric (A1) Lamb mode resonators based on LiNbO3 thin films face specific challenges, such as inadequate mechanical stability, limited power capacity, and the presence of multiple spurious modes, which restrict their applicability in a broader context. In this paper, we present an innovative design for A1 Lamb mode resonators that incorporates a support-pillar structure. Integration of support pillars enables the dissipation of spurious wave energy to the substrate, effectively mitigating unwanted spurious modes. Additionally, this novel approach involves anchoring the piezoelectric thin film to a supportive framework, consequently enhancing mechanical stability while simultaneously improving the heat dissipation capabilities of the core.
“…Some of these have already been used for different applications and have the potential for integration into mobile applications. Some examples of such sensors based on resonant gravimetry include film bulk acoustic resonators (FBARs) [12,13,14], quartz crystal microbalance (QCM) [15,16,17,18], surface acoustic wave (SAW) sensors [19,20,21,22], micro and nanocantilevers [23,24,25,26,27] and Capacitive Micromachined Ultrasound Transducers (CMUTs) [28,29,30,31,32,33]. CMUTs can be fabricated in different sizes and shapes with optimized features fulfilling needed mass sensitivity of the resonator, the limit of detection and signal to noise ratio (SNR).…”
A gravimetric gas detection device based on surface functionalized Capacitive Micromachined Ultrasound Transducers (CMUTs) was designed, fabricated and tested for detection of carbon dioxide (CO2) and sulfur dioxide (SO2) mixtures in nitrogen. The created measurement setup of continuous data collection, integrated with an in-situ Fourier Transform Infrared (FT-IR) spectroscopy, allows for better understanding of the mechanisms and molecular interactions with the sensing layer (methylated poly(ethylene)imine) and its need of surface functionalization for multiple gas detection. During experimentation with CO2 gases, weak molecular interactions were observed in spectroscopy data. Linear sensor response to frequency shift was observed with CO2 concentrations ranging from 0.16 vol % to 1 vol %. Moreover, the Raman and FT-IR spectroscopy data showed much stronger SO2 and the polymer interactions, molecules were bound by stronger forces and irreversibly changed the polymer film properties. However, the sensor change in resonance frequency in the tested region of 1 vol % to 5 vol % SO2 showed a linear response. This effect changed not only the device resonance frequency but also affected the magnitude of electroacoustic impedance which was used for differentiating the gas mixture of CO2, SO2, in dry N2.
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