Supramolecular complexes of Ni (II) and Co (II) 4‐aminobenzoate with 3‐cyanopyridine: Synthesis, spectroscopic characterization, crystal structure, and enzyme inhibitory properties
Abstract:Two new complexes, [M (AB)2(CP)2(H2O)2] (where M = Ni and Co AB = 4‐aminobenzoate and CP = cyanopyridine), were synthesized and characterized using different techniques (elemental analysis, FT‐IR spectrophotometer, LC/MS, single‐crystal X‐ray diffraction, and TGA/DTA analysis). As a result of X‐ray structural analysis, it was determined that complexes are isostructural. In the crystalline structures, MII ions are bridged with their carboxylate oxygen and aminopyridine nitrogen atoms and their symmetry‐related … Show more
“…11 Coordination compounds involving N-donor organic moieties such as aminopyridines and cyanopyridines possess interesting pharmacological properties, viz. anti-inflammatory, 12 anticancer, 13 antimicrobial, 14 etc. and hold unique places from a medicinal chemistry viewpoint.…”
Two new poly-nuclear coordination compounds of Zn(II) and Mn(II) viz. [Zn2(male)2(3-AMpy)4]•3H2O (1) and [Mn(H2O)2(μ-fum)(3-CNpy)2]n (2) (male = maleate, fum = fumarate, 3-AMpy = 3-aminopyridine, 3-CNpy = 3-cyanopyridine) have been synthesized...
“…11 Coordination compounds involving N-donor organic moieties such as aminopyridines and cyanopyridines possess interesting pharmacological properties, viz. anti-inflammatory, 12 anticancer, 13 antimicrobial, 14 etc. and hold unique places from a medicinal chemistry viewpoint.…”
Two new poly-nuclear coordination compounds of Zn(II) and Mn(II) viz. [Zn2(male)2(3-AMpy)4]•3H2O (1) and [Mn(H2O)2(μ-fum)(3-CNpy)2]n (2) (male = maleate, fum = fumarate, 3-AMpy = 3-aminopyridine, 3-CNpy = 3-cyanopyridine) have been synthesized...
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