Supramolecular chemistry of gold(I) thiocyanate complexes with thiophene, phosphine and isocyanide ligands, and the structure of 2,6-dimethylphenyl isocyanide

Perfluoroarylgold complexes

“…3) with Au-S distances of 3.529(4)Å. This general pattern was also observed in [Au(SCN)(2,6-NC 6 H 3 Me 2 )] (Au-S 3.459(2) A) and [Au(SCN)(2,3,6-NC 6 H 2 Me 3 )] (Au-S 3.938(2) and 3.719(2)Å) [72].…”

Copper and Gold Cyclic (Alkyl)(amino)carbene Complexes with Sub‐Microsecond Photoemissions: Structure and Substituent Effects on Redox and Luminescent Properties

“…[16] By contrast, the reaction of for a mono(carbene) complex, whereas the resonance for bis(carbene) complexes is shifted downfield to δ 250 ppm. [10,11] (7), N2-C28 1.130(10), C28-S1 1.693 (8); C1-Au1-S1 173.72(16), N2-C28-S1 174.5 (7), Au1-S1-C28 103.3 (2).…”

Supra-molecular synthons based on gold…π(arene) interactions

“…9a), chains with linear and zigzag topology are also known [15]. Chains may also be consolidated by an average of two Au…π(arene) interactions per molecule as found in the structure of bis[(2,6-xylylisocyano)thiocyanatogold(I)] [38] ( Fig. 9b).…”