Supramolecular architecture built of Co(II) and a tripodal ligand containing 1-D water tapes with (H<sub>2</sub>O)<sub>16</sub> cluster units

Li, Zhenpeng; Huang, Liang; Xi, Pinxian; Liu, Hongyan; Shi, Yanjun; Xie, Guoqiang; Xu, Min; Chen, Fengjuan; Zeng, Zhengzhi

doi:10.1080/00958972.2011.584342

Cited by 9 publications

(2 citation statements)

References 45 publications

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“…For example, both the water dimer and trimer have been found in the novel Mn(II) complex [42]. 1D water tapes with (H 2 O) 16 cluster units have been found in the novel Co(II) Complex [43]. A metal(II)-water chain and a 2D water-sulfate layer containing cyclic water octamers has been found in the tetranuclear Cu(II) complex [44].…”

Section: Crystalmentioning

confidence: 99%

Synthesis, structure and properties of three 1D d10 metal–organic coordination polymers with 5-amino-2,4,6-triiodoisophthalic acid

Zhang

Wang

Zhong

et al. 2015

Inorganica Chimica Acta

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Section: Crystalmentioning

confidence: 99%

Synthesis, structure and properties of three 1D d10 metal–organic coordination polymers with 5-amino-2,4,6-triiodoisophthalic acid

Zhang

Wang

Zhong

et al. 2015

Inorganica Chimica Acta

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“…For example, both the water dimer and trimer have been found in a Mn complex [58]. ID water tapes with (H2O)i6 cluster units have been found in a Co complex [59]. A ID metal-water chain and a 2D water-sulfate W.Liang et a\.…”

Section: Structure Description Of [Pb(5-msba)(phen)2]-91120 (3)mentioning

confidence: 99%

Positional isomeric and N-donor auxiliary chelating ligand effect on engineering crystalline architectures of four lead(II) complexes with diverse fluorescent properties

Liang

Zhong

Pan

et al. 2013

Journal of Coordination Chemistry

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This work presents an investigation on the positions of the substituent and N-donor auxiliary chelating ligand (bipy/phen) effect on engineering of crystalline architectures of four Pb(II) complexes with a pair of methyl-substituted 3-sulfobenzoic isomers: [Pb(4-msba)(phen)(H2O)] (1), [Pb (4-msba)(bipy)(H2O)]-H2O (2), [Pb(5-msba)(phen)2] 9H2O (3), and [Pb2(5-msba)2(bipy)2(H2O)2] (4) (4/5-msba = 4/5-methyl-3-sulfobenzoate, phen= 1,10-phenanthroline and bipy = 2,2'-bipyridine). The lead(II) ions exhibit hemidirected geometry in 1-4. The positions of the methyl as well as the auxiliary chelating ligands infiuence coordination modes of the sulfonates and thus determine the architectures. As the position of methyl in aromatic ring changes from 4 to 5, the structures change from 2-D sheet-like compounds for 1 and 2 to 0-D dimeric species for 3 and 4. A water cluster (H20)is exists in 3, which flirther assembles into a water tape with a new pattern T4(3)4(3)10(3) A4. Complex 3 loses crystallinity rapidly in the open air and turns into [Pb(5-msba)(phen)2] 2H2O (3A). Thermal stabilities and solid state fluorescent properties of 1, 2, 3A, and 4 have been studied.

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Synthesis, Structures and Properties of Two New Coordination Polymers with Unprecedented Water Cluster

et al. 2014

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Two new complexes, [Eu 2 (NIPH) 2 (H 2 O) 14 ](HNIPH) 2 (H 2 O) 7 (1) [Co 2 (abtc)(phen) 4 (H 2 O)]Á12(H 2 O) (2) (H 2 NIPH = 5-nitroisophthalic acid, H 4abtc = 3,3 0 ,5,5 0 -azobenzenetetracarboxylic acid, phen = 1,10-phenanthroline, DMF = N,N 0 -dimethylformamide) have been synthesized and characterized by infrared spectrum, thermal gravimetric analysis, X-ray single crystal diffraction and photoluminescence properties. Complex 1 upon slow evaporation at room temperature gave a 0-D structure, and seven independent water molecules and their equivalent held together by hydrogen bonds with an ordered proton arrangement form a 1-D hydrogen-bonded water tape. An unusual water tape notated T10(0)A0 is observed in 2. A 1-D water tape by connecting five-ten-five membered water rings through hydrogen bonds. Multiple hydrogen bonds and p-p stacking interactions play important roles in the formation of the 3-D networks. Fascinatingly, these lattice water molecules display unprecedented water cluster and play important roles in the stabilizing the whole network.Keywords 5-Nitroisophthalic acid Á 3,3 0 ,5,5 0 -Azobenzenetetracarboxylic acid Á Water cluster Á Fluorescence Electronic supplementary material The online version of this article (

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Supramolecular architecture built of Co(II) and a tripodal ligand containing 1-D water tapes with (H₂O)₁₆ cluster units

Cited by 9 publications

References 45 publications

Synthesis, structure and properties of three 1D d10 metal–organic coordination polymers with 5-amino-2,4,6-triiodoisophthalic acid

Synthesis, structure and properties of three 1D d10 metal–organic coordination polymers with 5-amino-2,4,6-triiodoisophthalic acid

Positional isomeric and N-donor auxiliary chelating ligand effect on engineering crystalline architectures of four lead(II) complexes with diverse fluorescent properties

Synthesis, Structures and Properties of Two New Coordination Polymers with Unprecedented Water Cluster

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Supramolecular architecture built of Co(II) and a tripodal ligand containing 1-D water tapes with (H2O)16 cluster units

Cited by 9 publications

References 45 publications

Synthesis, structure and properties of three 1D d10 metal–organic coordination polymers with 5-amino-2,4,6-triiodoisophthalic acid

Synthesis, structure and properties of three 1D d10 metal–organic coordination polymers with 5-amino-2,4,6-triiodoisophthalic acid

Positional isomeric and N-donor auxiliary chelating ligand effect on engineering crystalline architectures of four lead(II) complexes with diverse fluorescent properties

Synthesis, Structures and Properties of Two New Coordination Polymers with Unprecedented Water Cluster

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Supramolecular architecture built of Co(II) and a tripodal ligand containing 1-D water tapes with (H₂O)₁₆ cluster units