Suppressing Non‐Radiative Relaxation through Single‐Atom Metal Modification for Enhanced Fluorescence Efficiency in Molybdenum Disulfide Quantum Dots

Abstract

To enhance the fluorescence efficiency of semiconductor nanocrystal quantum dots (QDs), strategies via enhancing photo-absorption and eliminating non-radiative relaxation have been proposed. In this study, we demonstrate that fluorescence efficiency of molybdenum disulfide quantum dots (MoS 2 QDs) can be enhanced by single-atom metal (Au, Ag, Pt, Cu) modification.Four-fold enhancement of the fluorescence emission of MoS 2 QDs is observed with single-atom Au modification. The underlying mechanism is ascribed to the passivation of non-radiative surface states owing to the new defect energy level of Au in the forbidden band that can trap excess electrons in n-type MoS 2 , increasing the recombination probability of conduction band electrons with valence band holes of MoS 2 . Our results open an avenue for enhancing the fluorescence efficiency of QDs via the modification of atomically dispersed metals, and extend their scopes and potentials in a fundamental way for economic efficiency and stability of single-atom metals.

Extremely Enhanced Photoluminescence in MoS2-Derived Quantum Sheets

“…Surface passivation increases the recombination probability of electrons and holes, improving the PL intensity of QSs. 27 defects and adjust the electronic state of MoS 2 to improve the PL stability. 23 The use of oxygen, nitrogen, mercaptan, and other molecules for filling vacancies and improving PL properties has been reported.…”