Supporting‐Electrolyte‐Free Electrochemical Methoxymethylation of Alcohols Using a 3D‐Printed Electrosynthesis Continuous Flow Cell System

Melis, Carlo G. W. van; Penny, Matthew R.; Garcia, Anthony D.; Petti, Alessia; Dobbs, Adrian P.; Hilton, Stephen T.; Lam, Kevin

doi:10.1002/celc.201900815

Cited by 52 publications

(40 citation statements)

References 22 publications

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“…Conversely, continuous flow electrochemical reactors generate a homogeneous electric field throughout the entire solution as it is entirely situated between the electrodes. Several groups have developed their own continuous flow reactors 71,[85][86][87][88][89][90][91][92][93][94][95][96][97][98][99] with commercial reactors also being available (Fig. 5e).…”

Section: Continuous Reactor Vesselsmentioning

confidence: 99%

Making electrochemistry easily accessible to the synthetic chemist

et al. 2020

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Section: Continuous Reactor Vesselsmentioning

confidence: 99%

Making electrochemistry easily accessible to the synthetic chemist

et al. 2020

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“… 13 Recently, a novel 3D-printed flow reactor was designed by Lam and Hilton that is fully integrated with ElectraSyn 2.0. 58 This reactor was demonstrated in the electrolyte-free electrochemical methoxymethylation of alcohols ( Figure 15 ).…”

Section: Electrochemistrymentioning

confidence: 99%

Section: Electrochemistrymentioning

confidence: 99%

New Redox Strategies in Organic Synthesis by Means of Electrochemistry and Photochemistry

et al. 2020

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As the breadth of radical chemistry grows, new means to promote and regulate single-electron redox activities play increasingly important roles in driving modern synthetic innovation. In this regard, photochemistry and electrochemistry—both considered as niche fields for decades—have seen an explosive renewal of interest in recent years and gradually have become a cornerstone of organic chemistry. In this Outlook article, we examine the current state-of-the-art in the areas of electrochemistry and photochemistry, as well as the nascent area of electrophotochemistry. These techniques employ external stimuli to activate organic molecules and imbue privileged control of reaction progress and selectivity that is challenging to traditional chemical methods. Thus, they provide alternative entries to known and new reactive intermediates and enable distinct synthetic strategies that were previously unimaginable. Of the many hallmarks, electro- and photochemistry are often classified as “green” technologies, promoting organic reactions under mild conditions without the necessity for potent and wasteful oxidants and reductants. This Outlook reviews the most recent growth of these fields with special emphasis on conceptual advances that have given rise to enhanced accessibility to the tools of the modern chemical trade.

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“…Low expenses and wide availability of printers render the FDM particularly suitable for the manufacture of cells. Most frequently used filaments are polylactic acid (PLA), [8 , 7 , [14] , [15] , [16] , [17] , [18] , [19] acrylonitrile butadiene styrene (ABS), [20] , [21] , [22] , [23] , [24] , [25] , [26] , [27] , [28] , [29] polypropylene [30 – 32] , and polyesters [33] . Cells manufactured by FDM 3DP involve multitude of functionalities and have found use in a broad range of electrochemical processes and applications, which are summarized in Table 1 .…”

Section: Introductionmentioning

confidence: 99%