Sulfonate-Grafted Porous Polymer Networks for Preferential CO<sub>2</sub> Adsorption at Low Pressure

Lü, Weigang; Yuan, Daqiang; Sculley, Julian P.; Zhao, Dan; Krishna, Rajamani; Zhou, Hong‐Cai

doi:10.1021/ja2087773

Cited by 528 publications

(449 citation statements)

References 46 publications

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“…The CO 2 -philic functionalities are introduced into the porous polymers through ''knitting'' method in recent research studies. The functionalities include amino (-NH 2 ), acetyl (-COCH 3 ), formyl (-CHO) and nitro (-NO 2 ) groups (He et al 2015;Lu et al 2011). Additionally, the introduction of N 2 -rich polar moieties such as carbazole and triazine groups is also an impressive route to increase CO 2 adsorption capacity.…”

Section: Microporous Organic Polymers (Mops)mentioning

confidence: 99%

“…The higher microporosity and impregnation of adsorbent material with N-functionality or carboxylic acid group elevate the heat of CO 2 adsorption for various adsorbent materials (Gadipelli and Guo 2015). Lu et al (2011) grafted PPN with sulfonic acid and its lithium salt, which significantly increased the CO 2 -uptake capacity and isosteric heat of CO 2 adsorption under ambient conditions. Multi-walled carbon nanotubes (CNTs) and amine-grafted CNT presented heats of CO 2 adsorption around 11.8 and 18.9 kJ mol -1 , respectively, which revealed the effect of incorporation of amine on heat of CO 2 adsorption.…”

Section: Heat Of Co 2 Adsorption Of the Adsorbentsmentioning

confidence: 99%

See 1 more Smart Citation

Feasibility of CO2 adsorption by solid adsorbents: a review on low-temperature systems

Younas

Sohail

Leong

et al. 2016

Int. J. Environ. Sci. Technol.

186

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In the last few decades of industrialization, the concentration of CO 2 in the atmosphere had increased rapidly. Different organizations have invested considerable funds in research activities worldwide for CO 2 capture and storage. To date, significant work has been done and various technologies have been proposed for CO 2 capture and storage. Both adsorption and absorption are promising techniques for CO 2 capture, but low-temperature adsorption processes using solid adsorbents are the prevailing technique nowadays. In this review paper, a variety of adsorbents such as carbonaceous materials, dry alkali metal-based sorbents, zeolites, metal-organic frameworks (MOFs) and microporous organic polymers (MOPs) have been studied. Various methods of chemical or physical modification and the effects of supporting materials have been discussed to enhance CO 2 capture capacity of these adsorbents. Low-temperature (\100°C) adsorption processes for CO 2 capture are critically analyzed and concluded on the basis of information available so far in the literature. All the information in CO 2 adsorption using different routes has been discussed, summarized and thoroughly presented in this review article. The most important comparative study of relatively new material MOFs and MOPs is carried out between the groups and with other sorbent as well.

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Section: Microporous Organic Polymers (Mops)mentioning

confidence: 99%

Section: Heat Of Co 2 Adsorption Of the Adsorbentsmentioning

confidence: 99%

Feasibility of CO2 adsorption by solid adsorbents: a review on low-temperature systems

Younas

Sohail

Leong

et al. 2016

Int. J. Environ. Sci. Technol.

186

View full text Add to dashboard Cite

show abstract

“…), another subfamily of porous material, has also been proposed. [71][72][73][74] From these types of materials, we discuss selected ones that offer the best compromise between selectivity, uptake, kinetics and the energy input for desorption in CO 2 capture.…”

Section: Discussionmentioning

confidence: 99%

Low concentration CO2 capture using physical adsorbents: Are metal–organic frameworks becoming the new benchmark materials?

Belmabkhout¹,

Guillerm²,

Eddaoudi³

2016

Chemical Engineering Journal

277

168

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KeywordsCO 2 capture, traces CO 2 removal, air capture, physical adsorbents, MOFs AbstractThe capture and separation of traces and concentrated CO 2 from important commodities such as CH 4 , H 2 , O 2 and N 2, is becoming important in many areas related to energy security and environmental sustainability. While trace CO 2 concentration removal applications have been modestly studied for decades, the spike in interest in the capture of concentrated CO 2 was motivated by the need for new energy vectors to replace highly concentrated carbon fuels and the necessity to reduce emissions from fossil fuel-fired power plants. CO 2 capture from various gas streams, at different concentrations, using physical adsorbents, such as activated carbon, zeolites, and metal-organic frameworks (MOFs), is attractive. However, the adsorbents must be designed with consideration of many parameters including CO 2 affinity, kinetics, energetics, stability, capture mechanism, in addition to cost. Here, we perform a systematic analysis regarding the key technical parameters that are required for the best CO 2 capture performance using physical adsorbents. We also experimentally demonstrate a suitable 2 material model of Metal Organic Framework as advanced adsorbents with unprecedented properties for CO 2 capture in a wide range of CO 2 concentration. These recently developed class of MOF adsorbents represent a breakthrough finding in the removal of traces CO 2 using physical adsorption.This platform shows colossal tuning potential for more efficient separation agents.

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“…CO 2 -uptake capacity of a metal oxide is primarily dominated by the factors such as surface area, pore volume, pore functionality and pore size [28]. BET surface area measurement, pore volume and average pore sizes presented in Table 2 indicates the significant role of CO 2 to influence the particle structure.…”

Section: -40mentioning

confidence: 98%

An experimental investigation of mesoporous MgO as a potential pre-combustion CO2 sorbent

Kumar

Saxena

Drozd

et al. 2015

Mater Renew Sustain Energy

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We examined the CO 2 capture capacity of mesoporous MgO (325 mesh size, surface area = 95.08 ± 1.5 m 2 /g) as a potential pre-combustion CO 2 sorbent. Our results show that 96.96 % of MgO was converted to MgCO 3 at 350°C and 10 bars CO 2 pressure. The sorbent could be completely regenerated at 550°C under argon flow. The sorption rate parameters such as surface area and pore size were investigated.

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Sulfonate-Grafted Porous Polymer Networks for Preferential CO₂ Adsorption at Low Pressure

Cited by 528 publications

References 46 publications

Feasibility of CO2 adsorption by solid adsorbents: a review on low-temperature systems

Feasibility of CO2 adsorption by solid adsorbents: a review on low-temperature systems

Low concentration CO2 capture using physical adsorbents: Are metal–organic frameworks becoming the new benchmark materials?

An experimental investigation of mesoporous MgO as a potential pre-combustion CO2 sorbent

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Sulfonate-Grafted Porous Polymer Networks for Preferential CO2 Adsorption at Low Pressure

Cited by 528 publications

References 46 publications

Feasibility of CO2 adsorption by solid adsorbents: a review on low-temperature systems

Feasibility of CO2 adsorption by solid adsorbents: a review on low-temperature systems

Low concentration CO2 capture using physical adsorbents: Are metal–organic frameworks becoming the new benchmark materials?

An experimental investigation of mesoporous MgO as a potential pre-combustion CO2 sorbent

Contact Info

Product

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Sulfonate-Grafted Porous Polymer Networks for Preferential CO₂ Adsorption at Low Pressure