Study on the Structure and Dielectric Properties of Zeolite/LDPE Nanocomposite under Thermal Aging

Abstract

Nanodoping is an effective way to improve the dielectric properties and the aging resistance of polyethylene. Nano-zeolite has a nano-level porous structure and larger specific surface area than ordinary nano-inorganic oxide, which can be used to improve dielectric properties of low-density polyethylene (LDPE) nanocomposite. The zeolite/LDPE nanocomposites were prepared and subjected to thermal aging treatment to obtain samples with different aging time. Using scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FTIR) and the differential scanning calorimetry (DSC) test to study the microscopic and structure characteristics, it was found that nano-zeolite doping can effectively reduce the thermal aging damage to the internal structure of the nanocomposite; carbonyl and hydroxyl decreased significantly during the thermal aging time, and the crystallinity effectively improved. Nano-zeolite doping significantly improved the morphology and strengthened the aging resistance of the nanocomposite. In the dielectric strength test, it was found that nanodoping can effectively improve the direct current (DC) and alternating current (AC) breakdown field strength and the stability after the thermal aging. The dielectric constant of nanocomposite can be reduced, and the dielectric loss had no obvious change during the aging process. Moreover, the zeolite/LDPE nanocomposite with the doping concentration of 1 wt % had the best performance, for the nano-zeolite was better dispersed.

Volume Resistivity of Viton Polymer under Thermal Aging

“…This is commonly known as thermal aging, which can drastically change the electrical properties and the chemical structure of the polymer. Exposed to the high-temperature environmental condition for long working hours, insulation polymers tend to lose their dielectric properties, leading to insulation failure [ 20 , 21 , 22 ]. It is necessary to find out the breakdown hours or insulation failure due to thermal aging by measuring the resistivity of polymeric materials.…”