“…At a low L/A ratio or low sodium content, the geopolymeric structure at molecular level contains a number of ion holes due to the insufficient sodium for negative charge balancing. This defect promotes ionic conduction which plays a role in the enhancement of electrical conductivity in a high frequency range [21]. The FA geopolymer paste with an L/A ratio of 0.4 gives the highest level of electrical conductivity up to 10 3 S/cm comparing with lower values around 910 4 , 710 4 , and 510 4 S/cm of geopolymer pastes with the L/A ratios of 0.6, 0.5, and 0.7, respectively.…”
Section: Electrical Properties Of Geopolymer Pastesmentioning
The electrical conductivity and dielectric property of fly ash geopolymer pastes in a frequency range of 100 Hz-10 MHz were studied. The effects of the liquid alkali solution to ash ratios (L/A) were analyzed. The mineralogical compositions and microstructures of fly ash geopolymer materials were also investigated using X-ray diffraction (XRD) and scanning electron microscopy (SEM). The 10 mol sodium hydroxide solution and sodium silicate solution at a sodium silicate-to-sodium hydroxide ratio of 1.0 were used in making geopolymer pastes. The pastes were cured at 40C. It is found that the electrical conductivity and dielectric constant are dependent on the frequency range and L/A ratios. The conductivity increases but the dielectric constant decreases with increasing frequency.
“…At a low L/A ratio or low sodium content, the geopolymeric structure at molecular level contains a number of ion holes due to the insufficient sodium for negative charge balancing. This defect promotes ionic conduction which plays a role in the enhancement of electrical conductivity in a high frequency range [21]. The FA geopolymer paste with an L/A ratio of 0.4 gives the highest level of electrical conductivity up to 10 3 S/cm comparing with lower values around 910 4 , 710 4 , and 510 4 S/cm of geopolymer pastes with the L/A ratios of 0.6, 0.5, and 0.7, respectively.…”
Section: Electrical Properties Of Geopolymer Pastesmentioning
The electrical conductivity and dielectric property of fly ash geopolymer pastes in a frequency range of 100 Hz-10 MHz were studied. The effects of the liquid alkali solution to ash ratios (L/A) were analyzed. The mineralogical compositions and microstructures of fly ash geopolymer materials were also investigated using X-ray diffraction (XRD) and scanning electron microscopy (SEM). The 10 mol sodium hydroxide solution and sodium silicate solution at a sodium silicate-to-sodium hydroxide ratio of 1.0 were used in making geopolymer pastes. The pastes were cured at 40C. It is found that the electrical conductivity and dielectric constant are dependent on the frequency range and L/A ratios. The conductivity increases but the dielectric constant decreases with increasing frequency.
“…Cement is a low-cost, mechanically rugged and electrically conducting material which can be rendered n-type or p-type by the use of appropriate admixtures, such as short carbon fibers (which contribute holes) for attaining p-type cement and short steel fibers (which contribute electrons) for attaining n-type cement [41][42][43][44][45]. (Cement itself is weakly n-type in relation to electronic/ionic conduction (41).)…”
Section: Cement-matrix Compositesmentioning
confidence: 99%
“…The carbon fiber contributes to hole conduction [42][43][44], thus making the absolute thermoelectric power of the cement-matrix composite more positive [41]. By using intercalated carbon fiber, which provides even more holes, the absolute thermoelectric power becomes even more positive [59].…”
“…Many researchers have studied the thermoelectric properties of carbonfiber-reinforced cement-based materials. Sun et al [5,6] first reported on the Seebeck effect of carbon-fiber-reinforced cement (CFRC), and proposed the ionic, electronic, and hole conduction of CFRC. Chung et al [7][8][9] performed a considerable amount of research addressing the thermoelectric effects of CFRC.…”
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