“…Silicon is the second most abundant element in the Earth's crust (about 28% by mass) after oxygen and is present in teramole quantities in the oceans, primarily in the form of silicic acid (Armbrust, 2009; Ruecker & Kuemmerer, 2015; Struyf et al, 2010; Treguer et al, 1995). As such, it is only natural for silicon‐based materials to play a critical role in a large number of consumer goods and commodity chemicals, including polymers (adhesives, coatings, sealants, gels, foams, aerosols, encapsulants, and preservatives) (Li et al, 2021; Miao et al, 2022; Petric, 2018; Ruecker & Kuemmerer, 2015), semi‐conductors (Kim et al, 2011; Polikarpov & Yakimov, 2015; Reece et al, 2011), agrochemical and biomedical agents (Lazareva et al, 2018; Lazareva & Lazarev, 2015; Peng et al, 2014; Zhou et al, 2022). However, despite a high abundance of silicon and silicates in the Earth's crust and the large number of organosilicon compounds generated in laboratory settings, organosilicon species have not yet been found in nature either as primary or secondary metabolites, to the best of our knowledge, with the involvement of silicon in the biochemistry of many organisms remaining elusive (Petkowski et al, 2020).…”