“…With the concept of green environmental protection gradually becoming the consensus in the world, non-toxic, halogen-free, and DOI: 10.1002/mame.202200586 environmentally friendly flame retardant systems have attracted wide attention. [1,2] Currently, flame retardants in common use usually include intumescent flame retardants (e.g., ammonium polyphosphate and expandable graphite), [3][4][5] bio-based flame retardants (e.g., chitosan, lignin, alginate, and cyclodextrin), [6][7][8] and inorganic flame retardants (e.g., zinc borate and aluminum hydroxide). [9,10] For instance, a biomass melamine phytate has been used as a flame retardant, showing good compatibility with the rigid polyurethane foam (RPUF) matrix, and inhibiting the release of smoke (e.g., aromatic compounds, cyanide and CO), toxic gases and combustible gases (e.g., hydrocarbons and esters).…”