Study of the impact of bottles material and color on the presence of As III , As V , Sb III , Sb V and Cr VI in matrix-rich mineral water — Multielemental speciation analysis by HPLC/ICP-DRC-MS

Marcinkowska, Monika; Lorenc, Wiktor; Barałkiewicz, Danuta

doi:10.1016/j.microc.2016.11.022

Cited by 17 publications

(14 citation statements)

References 28 publications

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“…In around half of the water samples, the known species of As, Cr, and Sb were notably lower than the total element content; these results are different from the results obtained for mineral water samples in our previous experiments [9,16]. Results obtained for known species analysis in flavored and functional bottled drinking water samples are in good accordance with literature data [9,11,20,[27][28][29]. The toxic inorganic species of As(III), As(V), Cr(VI), Sb(III), and Sb(V) are important factors that influence the toxicity of these elements in the flavored and functional drinking water samples.…”

Section: Discussioncontrasting

confidence: 99%

“…Arsenic was detected in tested samples with the highest concentration among target elements. Obtained TAs, TCr, and TSb results are in a good accordance with the data available from the literature regarding those element concentrations in various soft drinks and mineral water samples [9,[22][23][24][25][26].…”

Section: Discussionsupporting

confidence: 88%

“…There is no visible trend in the relationship between TAs, TCr, and TSb or their species presence and concentration in bottled flavored and functional drinking water and the composition of those waters. In around half of the water samples, the known species of As, Cr, and Sb were notably lower than the total element content; these results are different from the results obtained for mineral water samples in our previous experiments [9,16]. Results obtained for known species analysis in flavored and functional bottled drinking water samples are in good accordance with literature data [9,11,20,[27][28][29].…”

Section: Discussioncontrasting

confidence: 50%

“…It is known that packing material can release certain elements such as As, Cr, or Sb into bottled water [6,7]. In the literature, one can find reports about the release of elements from various container materials such as polyethylene (PET), glass, aluminum, or steel into beverages such as mineral water, juice, or soft drinks [8][9][10]. It was reported that some water additives such as citric acid can affect both the amount and the species in which certain elements are leached from bottle material [11][12][13][14][15].…”

Section: Introductionmentioning

confidence: 99%

“…It was reported that some water additives such as citric acid can affect both the amount and the species in which certain elements are leached from bottle material [11][12][13][14][15]. In previous work, authors assessed the presence of toxic inorganic As, Cr, and Sb species in mineral water samples proving that those inorganic ionic species were present in that type of water [9,16]. Considering that flavored and functional drinking waters have a rich matrix in comparison to mineral water, they may also contain variable species of As, Cr, and Sb in complexed or other molecular structures.…”

Section: Introductionmentioning

confidence: 99%

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Total Versus Inorganic and Organic Species of As, Cr, and Sb in Flavored and Functional Drinking Waters: Analysis and Risk Assessment

et al. 2020

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Packing material can release certain elements such as As, Cr, or Sb into its content and, thus, contaminate the drinking water. The effect of As, Cr, and Sb on human health depends highly on the chemical species in which these elements are introduced into the body. For the above reasons quantification and speciation of As, Cr, and Sb in flavored and functional drinking water samples is an important issue. Total, inorganic, and organic species of As, Cr, and Sb including As(III), As(V), Cr(VI), Sb(III), and Sb(V) were studied in flavored and functional drinking waters. Analyses of total As, Cr, and Sb were conducted using inductively coupled plasma mass spectrometry (ICP-MS) according to ISO 17294-2:2016. The speciation analysis of arsenic, chromium, and antimony in bottled flavored and functional drinking waters was conducted with the use of the elemental (HPLC/ICP dynamic reaction cell (DRC) MS) and molecular (electrospray ionization MS/MS) mass spectrometry. Concentrations of total As, Cr, and Sb (µg∙L−1) in waters studied were in the ranges 0.0922 ± 0.0067 to 8.37 ± 0.52, 0.0474 ± 0.0014 to 1.310 ± 0.045, and 0.0797 ± 0.0026 to 1.145 ± 0.019, respectively. Speciation analysis showed that, apart from the toxic ionic species, known and unknown organic species were present in test samples. The risk assessment results proved that there is no risk associated with consumption of these tested beverages in terms of the non-carcinogenic effect of total and inorganic or organic species of As, Cr, and Sb.

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Section: Discussioncontrasting

confidence: 99%

Section: Discussionsupporting

confidence: 88%

Section: Discussioncontrasting

confidence: 50%

Section: Introductionmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

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Total Versus Inorganic and Organic Species of As, Cr, and Sb in Flavored and Functional Drinking Waters: Analysis and Risk Assessment

et al. 2020

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Impact of temperature and storage time on the migration of antimony from polyethylene terephthalate (PET) containers into bottled water in Qatar

Al-Otoum

Al-Ghouti

Costa

et al. 2017

Environ Monit Assess

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Prosperity in Qatar and the consequent stresses on water resources resulted in a sustainable increase in the bottled drinking water market. Reports on health concerns and possible migration of chemicals from the plastic material into the water have driven the current investigation. This study aims to address the extent of antimony (Sb) leaching from polyethylene terephthalate (PET) water bottles subject to temperature variations (24-50 °C) due to Qatar's hot climate and improper storage conditions. A representative basket including 66 different imported and locally produced water bottles was considered. The concentrations of Sb in bottled water ranged from 0.168 to 2.263 μg/L at 24 °C and from 0.240 to 6.110 μg/L at 50 °C. Antimony concentrations in PET bottles at 24 °C was significantly lower than those at 50 °C (p = 0.0142), indicating that the temperature was a principal factor affecting the release of Sb from the plastic into the water. Although the detected Sb amounts were below the guidelines endorsed by WHO and Qatar (standard 5 μg/L) at 24 °C, the concentration measured at 50 °C was higher than the recommended WHO values (6.11 μg/L).

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Antimony and PET bottles: Checking facts

Filella

2020

Chemosphere

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Study of the impact of bottles material and color on the presence of As III , As V , Sb III , Sb V and Cr VI in matrix-rich mineral water — Multielemental speciation analysis by HPLC/ICP-DRC-MS

Cited by 17 publications

References 28 publications

Total Versus Inorganic and Organic Species of As, Cr, and Sb in Flavored and Functional Drinking Waters: Analysis and Risk Assessment

Total Versus Inorganic and Organic Species of As, Cr, and Sb in Flavored and Functional Drinking Waters: Analysis and Risk Assessment

Impact of temperature and storage time on the migration of antimony from polyethylene terephthalate (PET) containers into bottled water in Qatar

Antimony and PET bottles: Checking facts

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