“…4 represents the UV-Vis spectrum of pristine and irradiated samples. The absorption peak shifts from UV towards the visible region which indicates a decrease in the band gap after irradiation [29,30,[38][39][40][41][42]. The shift to the absorption edge as a result irradiation, inferred the bond rupturing leading to scission, free radical formation, cross linking, etc., resulting into the formation of new bonds.…”