Study of Dynamics of Allyl Chloride-2-Butanone Binary System Using Time Domain Reflectometry

Sudake, Y. S.; Kamble, S. P.; Patil, S. S.; Khirade, P. W.; Mehrotra, S. C.

doi:10.5012/jkcs.2012.56.1.020

Cited by 9 publications

(2 citation statements)

References 26 publications

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“…Excess parameters. The general formula for calculating the excess parameters [15][16][17][18][19][20][21][22][23][24][25][26][27][28][29][30][31][32] is given below…”

Section: Discussionmentioning

confidence: 99%

Microwave dielectric relaxation & polarization study of binary mixture of methylethylketone with nitrobenzene

Maharolkar¹,

Murugkar²,

Khirade³

et al. 2019

Bull. Chem. Soc. Eth.

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Present paper reveals detailed study of dielectric relaxation and dielectric polarization and physicochemical study of binary polar-polar liquid mixture i.e. dielectric constant, relaxation time, viscosity, density of methylethylketone (MEK) with nitrobenzene (NB) at 303 K. The measured dielectric and physicochemical parameters employed to acquire additional derived properties like Bruggeman factor, molar refraction and excess properties like static dielectric constant, excess inverse relaxation time, excess molar volume, excess viscosity, excess molar refraction, Gibbs free energy, and enthalpy of activation. The variation of this parameters with composition of these quantities has been used to explain the type, strength and nature of intermolecular interactions between MEK+NB binary mixture. Attained results authenticate that there are strong hydrogen-bond interactions between unlike molecules of different groups of MEK+NB mixtures and that 1:1 complexes are produced and strength of intermolecular interaction rises with rise in concentration of MEK.

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“…Excess parameters. The general formula for calculating the excess parameters [15][16][17][18][19][20][21][22][23][24][25][26][27][28][29][30][31][32] is given below…”

Section: Discussionmentioning

confidence: 99%

Microwave dielectric relaxation & polarization study of binary mixture of methylethylketone with nitrobenzene

Maharolkar¹,

Murugkar²,

Khirade³

et al. 2019

Bull. Chem. Soc. Eth.

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show abstract

“…The latter indicates that the important dispersion effects are also optimized in that environment, as alluded to the fitting of apolar components earlier. That such rigid framework may exist in concentrated solutions in metastable states around the precipitation conditions in the form of not only the metal-ion bound tartrate anion but also of the strong hydrogen-bond to the anionic O-atom is made probable also when considering dielectric [48,49] and other properties of the 2-butanone (MEK) solvent used in the crystallization experiment. Among other features MEK is known to have moderate relative permittivity aiding in sustaining cationic-anionic association, as well as strong ionic H-bridges.…”

Section: Hydrogen Bonding In Diastereomeric Complexes 3 Andmentioning

confidence: 99%

Optical Resolution of Dimethyl α-Hydroxy-Arylmethylphosphonates via Diastereomer Complex Formation Using Calcium Hydrogen O,O′-Dibenzoyl-(2R,3R)-Tartrate; X-Ray Analysis of the Complexes and Products

et al. 2020

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Two dimethyl α-hydroxy-arylmethylphosphonates (aryl = Ph and 2-MeOPh) were subjected to optical resolution via diastereomer complex formation applying the acidic calcium salt of O,O′-dibenzoyl-(2R,3R)-tartaric acid as the resolving agent. The dominating diastereomer complexes, whose structure was determined by single crystal X-ray measurements, were obtained in 96% and 68% diastereomer excess values, respectively. After decomposing the diastereomer formations by extraction, and after recrystallizations, the major enantiomer (S and R, respectively) of the α-hydroxyphosphonates were prepared in enantiomeric excess values of 96% and 68%, respectively. The stereostructure of the two α-hydroxy-arylmethylphosphonates was again established by X-ray measurements. Detailed study on the X-ray data allowed valuable conclusions on the nature of the coordination in the complexes (intermolecular interactions), and on the H-bonding.

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Static dielectric constant of 3-chloro-1-propene

Wohlfarth¹

2015

Static Dielectric Constants of Pure Liquids and Binary Liquid Mixtures

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Study of Dynamics of Allyl Chloride-2-Butanone Binary System Using Time Domain Reflectometry

Cited by 9 publications

References 26 publications

Microwave dielectric relaxation & polarization study of binary mixture of methylethylketone with nitrobenzene

Microwave dielectric relaxation & polarization study of binary mixture of methylethylketone with nitrobenzene

Optical Resolution of Dimethyl α-Hydroxy-Arylmethylphosphonates via Diastereomer Complex Formation Using Calcium Hydrogen O,O′-Dibenzoyl-(2R,3R)-Tartrate; X-Ray Analysis of the Complexes and Products

Static dielectric constant of 3-chloro-1-propene

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