Study of Asphaltene Structure Precipitated from Oil Sands

Abstract

<p>In the paper microscopic structure and physicochemical characteristics of asphaltenes were investigated. Asphaltene was precipitated from natural bitumen of oil sand of Munaily-Mola deposit using organic solvent of petroleum ether. According to results of our work, we found that the largest yield of asphaltens was reached by using the petroleum ether in 40-fold amount in relation to the initial hitch of bitumen. Chemical composition of precipitated asphaltenes aggregates were studied on FT-Infra red spectrometer Spectrum-65 at 450-4000 cm<sup>-1</sup>. At the Infrared spectrum, that the broad absorption band of asphaltenes at 3000-3600 cm-1 are characterizing the presence of polycyclic aromatic hydrocarbons and aliphatic chains in the samples of asphaltens. Elemental composition of the samples of asphaltenes on the installation of X-ray fluorescent spectrometer "Focus-M2". Also found the presence of two crystalline phases. One - quartz content is less than one percent. Another phase is also present in very small quantities and is represented by a single line of diffraction d = 4.158 Å. The microstructures and microanalysis of asphaltenes were investigated with an scanning electron microscopy (Quanta 3D 200i) at an accelerated voltage of 20 kV and a pressure of 0.003 Pa at National Nanotechnological Laboratory of Open Type of Kazakh National University. Microscopic images showed that the asphaltenes have a medium-ordered structure, the main component of the surface is<br /> represented by amorphous carbon.</p>

Selection of Solvents for the Removal of Asphaltene–Resin–Paraffin Deposits

“…where m 1 is the mass of the studied sediment sample before contact with the reagent, g, and m 2 is the mass of the insoluble sediment residue after contact with the reagent, g. The dissolving power of the reagent (C) in g/cm 3 was calculated as:…”

“…They form as a result of changes in thermobaric conditions. When the temperature in the wellbore drops to the temperature at which crystallization is initiated, paraffin crystals begin to form in the oil, which are the centers of crystallization [1][2][3][4][5].…”

High Temperature Transformation of Tar-Asphaltene Components of Bituminous Sand Bitumen

“…Aromatics in liquid product can be created either from naphthenes or side chains in aromatic bitumen. The olefins from cracked side chains can build aromatics by free-radical additions followed by rearrangements [8][9][10][11]. The calculations data determined the most stable conformation of tars and asphaltenes molecules.…”

Changing the Structure of Resin-Asphaltenes Molecules in Cracking

“…The color of crude oils and residues is due to the combined effect of neutral resins and asphaltenes. The black color of some crude oils and residues is related to the presence of asphaltenes that are not properly peptized [8,10].…”

“…It is still debated whether the physical nature of asphaltenes presents as an aggregate, a colloid, or an association with resins. Asphaltenes are a contentious area among researchers, with long-standing battles still raging [10,12]. Asphaltenes are very sensitive to atmospheric oxygen.…”