Abstract:The 3Bi 2 O 3 ·5B 2 O 3 -Nd 2 O 3 ·3B 2 O 3 system was studied using DTA, XRD, and electrical conductivity and heat properties measured. A new ternary compound was revealed in the system. Formation of a new compound expands an area of glass formation towards non-glass forming boundary binary compounds. It found that obtained materials possess semiconductor properties as distinct from initial 3Bi 2 O 3 ·5B 2 O 3 , Nd 2 O 3 ·3B 2 O 3
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