Novel polyimide-g-Fe 2 O 3 hybrid nanocomposite films (PI/g-Fe 2 O 3 ) has been developed from the poly (amic acid) salt of oxydianiline with different weight percentages (5, 10, 15 wt %) of g-Fe 2 O 3 using tetrahydrofuran (THF) and N,N-dimethylacetamide (DMAc) as aprotic solvents. The prepared polyimide-g-Fe 2 O 3 nanocomposite films were characterized for their structure, morphology, and thermal behavior employing Fourier transform infrared spectroscopy (FTIR), scanning electron micrograph (SEM), transmission electron micrograph (TEM), X-ray diffraction (XRD),