Abstract:A donor-acceptor compound based on N, N,N′,2,4, has been synthesized. The crystal structure of the black 1:1 complex formed between TMPD and TCNB has been determined by single crystal X-ray diffraction at room temperature. The compound crystallizes in the triclinic space group P-1 with cell dimensions: a = 7.4986(15) Å, b = 7.6772(11) Å, c = 8.0764(15) Å, α = 78.822(12)°, β = 83.3779(19)°, γ = 86.289(17)°. TMPD and TCNB molecules are stacked alternately in infinite columns along the a-axis.The structure does n… Show more
“…27 The doping of this motif through oxidation is a well-studied feature, and the hereby generated radical cations show promising stability as conductive organic materials for charge transport or storage. [28][29][30] Organic salts based on TMPD as the electron donor and tetracyanoquinodimethane (TCNQ) as the electron acceptor show high electrical conductivities. 31 Herein, we demonstrate that the Wurster motif can be embedded into different COFs, defined by using two different linear linker molecules.…”
Section: Wurster-type Compounds Are Electron-rich Molecules Derived Fmentioning
Covalent organic frameworks (COFs) define a versatile structural paradigm combining attractive properties such as crystallinity, porosity, and chemical and structural modularity which are valuable for various applications. For the incorporation...
“…27 The doping of this motif through oxidation is a well-studied feature, and the hereby generated radical cations show promising stability as conductive organic materials for charge transport or storage. [28][29][30] Organic salts based on TMPD as the electron donor and tetracyanoquinodimethane (TCNQ) as the electron acceptor show high electrical conductivities. 31 Herein, we demonstrate that the Wurster motif can be embedded into different COFs, defined by using two different linear linker molecules.…”
Section: Wurster-type Compounds Are Electron-rich Molecules Derived Fmentioning
Covalent organic frameworks (COFs) define a versatile structural paradigm combining attractive properties such as crystallinity, porosity, and chemical and structural modularity which are valuable for various applications. For the incorporation...
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