Charge transfer adducts of rare earth 3,5-dinitrobenzoates with N,N,N′,N′-tetramethyl-p-phenylenediamine

Koroteev, Pavel S.; Ефимов, Н. Н.; Ugolkova, E. A.; Dobrokhotova, Zhanna V.; Минин, В. В.; Новоторцев, В. М.

doi:10.1016/j.ica.2015.11.025

Cited by 3 publications

(1 citation statement)

References 38 publications

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“…In this context, several binuclear lanthanides 3,5-dinitrobenzoates with N,N-dimethylaniline (DMA) [ 103 ], 1,2-phenylenediamine [ 57 ], and N,N,N′,N′-tetramethyl-p-phenylenediamine were synthesized by Koroteev et al [ 104 ], which showed interesting charge transfer properties that give rise to magnetism according to the amount of charge transfer, where Dysprosium complexes even show a single-molecule magnetic behavior. Moreover, coordination polymers based on bridged dicyanamido-metal(II) building units were synthesized, with their structural and magnetic characteristics rationalized via DFT calculations, by Mautner et al [ 105 ].…”

Section: Theoretical Study Of 35- and 24-dinitrobenzoate Metal Complexesmentioning

confidence: 99%

Biological Activity of Complexes Involving Nitro-Containing Ligands and Crystallographic-Theoretical Description of 3,5-DNB Complexes

Fonseca-López,

Lozano,

Macías

et al. 2024

IJMS

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Drug resistance in infectious diseases developed by bacteria and fungi is an important issue since it is necessary to further develop novel compounds with biological activity that counteract this problem. In addition, new pharmaceutical compounds with lower secondary effects to treat cancer are needed. Coordination compounds appear to be accessible and promising alternatives aiming to overcome these problems. In this review, we summarize the recent literature on coordination compounds based on nitrobenzoic acid (NBA) as a ligand, its derivatives, and other nitro-containing ligands, which are widely employed owing to their versatility. Additionally, an analysis of crystallographic data is presented, unraveling the coordination preferences and the most effective crystallization methods to grow crystals of good quality. This underscores the significance of elucidating crystalline structures and utilizing computational calculations to deepen the comprehension of the electronic properties of coordination complexes.

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Section: Theoretical Study Of 35- and 24-dinitrobenzoate Metal Complexesmentioning

confidence: 99%

Biological Activity of Complexes Involving Nitro-Containing Ligands and Crystallographic-Theoretical Description of 3,5-DNB Complexes

Fonseca-López,

Lozano,

Macías

et al. 2024

IJMS

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Slow magnetic relaxation behaviors and diamagnetic dilution studies of a carboxyl bridged dinuclear dysprosium(III) complex

Liu,

Qiu,

et al. 2024

Journal of Rare Earths

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Charge transfer complexes of lanthanide 3,5-dinitrobenzoates and 1,2-phenylenediamine

Koroteev

Babeshkin

Efimov

2020

Journal of Molecular Structure

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Charge transfer adducts of rare earth 3,5-dinitrobenzoates with N,N,N′,N′-tetramethyl-p-phenylenediamine

Cited by 3 publications

References 38 publications

Biological Activity of Complexes Involving Nitro-Containing Ligands and Crystallographic-Theoretical Description of 3,5-DNB Complexes

Biological Activity of Complexes Involving Nitro-Containing Ligands and Crystallographic-Theoretical Description of 3,5-DNB Complexes

Slow magnetic relaxation behaviors and diamagnetic dilution studies of a carboxyl bridged dinuclear dysprosium(III) complex

Charge transfer complexes of lanthanide 3,5-dinitrobenzoates and 1,2-phenylenediamine

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