Studies in α-peptide formation by hydrogen migration polymerization I—Oligomers from maleamide, mesaconic acid α-methylester β-amide and mesaconamide

Bamford, C. H.; Eastmond, G. C.; Imanishi, Yukio

doi:10.1016/0032-3861(67)90076-6

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A-polypeptide Synthesis By the Hydrogen-migration1

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1969

1989

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Cited by 4 publications

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“…Recently, Bamford, et al 4 suggested the possibility of synthesizing an a-polypeptide by the hydrogen-migration polymerization of @substituted acrylamides. In their method, as shown in scheme (I), initial addition of a monomer anion to the carbon atom carrying an amide group of the double bond in a monomer or a higher oligomer, which is facilitated by a strongly electron-withdrawing substituent (X), and a subsequent proton transfer reaction are essential to obtain an a-polypeptide.…”

Section: A-polypeptide Synthesis By the Hydrogen-migrationmentioning

confidence: 99%