Structure–Thermodynamic‐Property Relationships in Cyanovinyl‐Based Microporous Polymer Networks for the Future Design of Advanced Carbon Capture Materials

Abstract

This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions.

Designed Synthesis of a 2D Porphyrin‐Based sp2Carbon‐Conjugated Covalent Organic Framework for Heterogeneous Photocatalysis

“…[14] This could be explained by the low reversibility of the formation of C = Cbonds and the synthesis of sp 2 carbon-linked COFs has been proven to be ab ig challenge. [14,15] Theu tilization of 2D COFs as heterogeneous photocatalysts has attracted al ot of attention recently,m ainly due to their intrinsic properties such as extended p-conjugated networks and aligned pore channels. [16] In principle,2 Ds p 2 carbon-linked COFs in which all the carbon atoms are fully conjugated can provide an interesting platform for heterogeneous photocatalysis.T he sp 2 carbon-conjugated skeletons can offer p conjugation along both the x and y directions, which may lead to am ore effective way in transmitting p conjugation across the 2D lattice and thus enhance electron delocalization.…”

Recent Trends in Covalent and Metal Organic Frameworks for Biomedical Applications

“…Yassin and coworkers demonstrated selective, high uptake (approx. 100 mg·g −1 ) of CO 2(g) in reusable MPNs, and showed that isosteric heats of absorption are proportional to the amount of functional group present [ 48 ]. Interestingly, given the amorphic nature of MPNs, this family showed high accessible surface area, robustness, and stability, even when compared to COFs [ 46 ].…”

Atomistic structure generation of covalent triazine-based polymers by molecular simulation

“…22,23 Another automated computational code for network generations called AMBUILD was proposed by Abbie et al and applied for model constructions of the PAF-1 framework, 24,25 aza-CMP 26 and other amorphous polymer networks. 27 However, the simulation research on the structures of CTF-type materials is rare, 28 especially for amorphous ones.…”