e present study considers the friction behavior of chemically deposited Ni-P-W coatings and optimization of the coating process parameters for minimum friction using Taguchi method. e study is carried out by varying the combination of four coating process parameters, namely, concentration of nickel source, concentration of reducing agent, concentration of tungsten source, and annealing temperature. e friction tests are conducted in a plate-on-roller con�guration by keeping the coated sample �xed against a rotating steel roller. e optimum combination of process parameters for minimum friction coefficient is obtained from the analysis of S/N ratio. Furthermore, a statistical analysis of variance reveals that the concentration of nickel source solution has the most signi�cant in�uence in controlling friction characteristics of Ni-P-W coating. e surface morphology and composition of coatings are also studied with the help of scanning electron microscopy, energy dispersed x-ray analysis, and x-ray diffraction analysis.