Scanning tunneling microscopy reveals that Si(112) reconstructs into quasiperiodic, nanometer-scale facets. Each sawtoothlike facet consists of a single unit cell wide reconstructed (111) terrace ͑7 3 7 or 5 3 5͒ opposed by a 60 to 110 Å wide (337) terrace. Nanofacets with a similar structure are also observed on Si(335), indicating that they are a general phenomenon for some range of vicinality towards [112]. The dimensions of these nanofacets suggest that Si(112) and Si(335) would be interesting substrates for the growth of corrugated superlattices. PACS numbers: 68.35.Bs, 61.16.Ch There is considerable interest in vicinal semiconductor surfaces as potential substrates for electronic device fabrication [1]. The uniformly spaced distribution of steps on a bulk-terminated vicinal surface is expected to promote step-flow growth during heteroepitaxy, and to provide a natural template for the growth of spatially confined structures. Unfortunately, vicinal semiconductor surfaces usually have terrace length distributions far from ideal. Such surfaces typically consist of large lowindex terraces separated by multilayer-height steps or step bunches [2][3][4], as opposed to periodic short terraces separated by single-layer-height steps (expected in the bulk-terminated case).Two high-index surfaces of Si, the (113) and (112), are thought to be relatively stable [4][5][6][7][8][9], and have therefore been used as substrates for the growth of high-quality III-V semiconductor epilayers [10,11] and possible quantum well wire arrays [12]. It has been shown via scanning tunneling microscopy (STM) studies that a complex reconstruction stabilizes the (113) surface orientation [7]. STM studies of the (112) surface, however, have yet to result in a model for the structure of this crystal face.[A model of the bulk-terminated (112) surface is shown in Fig. 1.] While one STM study of Si (112) observed a large number of (111) terraces along with a variety of other unidentified structures [13], a second study reported a ͑1 3 2͒ reconstruction with a longer period, pseudoordered domain structure [9]. In this Letter we report the results of our atomic-resolution STM study of Si(112). We find that clean, well-ordered surfaces exhibit a novel quasiperiodic reconstruction consisting of sawtoothlike nanofacets composed of short (337)-and (111)-oriented terraces. Furthermore, we observe a nearly identical reconstruction on Si(335), suggesting that this nanoscale faceting is a general phenomenon for some range of vicinality towards [112].The experiments were performed in ultrahigh vacuum (UHV) on Si wafers oriented to within 0.5 ± of (112) (as verified by x-ray diffraction) or (335). The samples were precleaned in a boiling 1:3 solution of H 2 O 2 and H 2 SO 4 , rinsed in distilled water, and then blown dry with nitrogen.Each sample was then mounted on a button heater in UHV, outgased at 600 ± C for 1 h, flashed to ഠ1150 ± C for 60 s with the pressure # 2 3 10 29 Torr, and then cooled at rates from 15 to ,0.5 ± C͞s. Atomic-resolution STM im...