2008
DOI: 10.1002/aic.11527
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Structure and kinetics of gas hydrates from methane/ethane/propane mixtures relevant to the design of natural gas hydrate storage and transport facilities

Abstract: in Wiley InterScience (www.interscience.wiley.com).The kinetics of gas hydrate growth from binary CH 4 /C 2 H 6 and CH 4 /C 3 H 8 and ternary CH 4 /C 2 H 6 /C 3 H 8 gas mixtures were obtained by the gas uptake method in a semibatch stirred vessel at constant pressure and a temperature of 273.7 K. These data are of interest for the design of facilities for natural gas storage and transportation in the solid (hydrate) state. During hydrate formation, samples from the gas phase were taken and analyzed by gas chro… Show more

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Cited by 161 publications
(176 citation statements)
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References 37 publications
(72 reference statements)
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“…15,16,42,43 Makogon and Holditch 39,40 reported that the presence of KHIs increased the temperature at which hydrates completely decomposed. It is noteworthy, too, that Schicks et al 43 reported that the hydrate decomposition line shifted toward higher temperatures with increasing concentrations of ethane and propane in a gas mixture.…”
Section: Articlementioning
confidence: 99%
“…15,16,42,43 Makogon and Holditch 39,40 reported that the presence of KHIs increased the temperature at which hydrates completely decomposed. It is noteworthy, too, that Schicks et al 43 reported that the hydrate decomposition line shifted toward higher temperatures with increasing concentrations of ethane and propane in a gas mixture.…”
Section: Articlementioning
confidence: 99%
“…The hydration number is the number of water molecules per guest molecule. It can be determined experimentally by simultaneously using powder X-ray diffraction and Raman spectroscopy on solid hydrate phase (Kumar et al, 2008(Kumar et al, , 2009aSum et al, 1997;Susilo et al, 2007;Uchida et al, 1999;Udachin et al, 2001) or by solid state NMR spectroscopy (Davidson et al, 1983;Ripmeester and Ratcliffe, 1988). In the presence of THF, the next equation is employed conversion of water to hydrates ðmol%Þ…”
Section: Conversion Of Water To Hydratementioning
confidence: 99%
“…The hydration number is the number of water molecules per guest molecule. It can be determined experimentally by simultaneously using powder X-ray diffraction and Raman spectroscopy on solid hydrate phase Kumar et al, 2008;Sum et al, 1997;Susilo et al, 2007a;Uchida et al, 1999;Udachin et al, 2007Udachin et al, , 2001 or by solid state NMR spectroscopy (Davidson et al, 1983;Ripmeester and Ratcliffe, 1988). In the presence of THF, the conversion of water to hydrate is determined by the next equation…”
Section: Conversion Of Water To Hydratementioning
confidence: 99%