Structural and electronic properties of transition-metal chalcogenides Mo₅S₄ nanowires*

Abstract

Transition-metal chalcogenide nanowires (TMCN) as a viable candidate for nanoscale applications have been attracting much attention for the last few decades. Starting from the rigid building block of M 6 octahedra (M = transition metal), depending on the way of connection between M 6 and decoration by chalcogenide atoms, multiple types of extended TMCN nanowires can be constructed based on some basic rules of backbone construction proposed here. Note that the well-known Chevrel-phase based M 6 X 6 and M 6 X 9 (X = chalcogenide atom) nanowires, which are among our proposed structures, have been successfully synthesized by experiment and well studied. More interestingly, based on the construction principles, we predict three new structural phases (the cap, edge, and C&E phases) of Mo5S4, one of which (the edge phase) has been obtained by top-down electron beam lithography on two-dimensional MoS2, and the C&E phase is yet to be synthesized but appears more stable than the edge phase. The stability of the new phases of Mo5S4 is further substantiated by crystal orbital overlapping population (COOP), phonon dispersion relation, and thermodynamic calculation. The barrier of the structural transition between different phases of Mo5S4 shows that it is very likely to realize an conversion from the experimentally achieved structure to the most stable C&E phase. The calculated electronic structure shows an interesting band nesting between valence and conduction bands of the C&E Mo5S4 phase, suggesting that such a nanowire structure can be well suitable for optoelectronic sensor applications.

One-dimensional metal thiophosphate nanowires by cluster assembly

“…[10][11][12][13] Intriguingly, most 1D transition metal chalcogenide nanowires exhibit metallic behavior, while a large number of TMD monolayers are semiconductors. [14][15][16] Transition metal halide nanowires present diverse electronic and magnetic properties, somewhat similar to reported 2D halides (e.g. CrI 3 , FeCl 2 , and VI 3 ) that comprise magnetic semiconductors and half metals.…”

Magnetic properties of a mixed spin-3/2 and spin-2 Ising octahedral chain

“…[1,2] This phenomenon has garnered tremendous attention as differing behaviors were demonstrated when compared to the bulk matter of the same element. [3,4] Specifically, the focus has been on one-dimensional (1D) magnetic spin chains with transition metal ions due to their inherent magnetic anisotropies and potential application for information storage at the molecular scale. [5][6][7][8][9][10][11] Galisova et al investigated the orthogonal-dimer chain using the classical transfermatrix approach.…”