1987
DOI: 10.1007/bf01188358
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Stress-strain behaviour of model networks in uniaxial tension and compression

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Cited by 24 publications
(10 citation statements)
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“…[1][2][3][4][5][6][7][8] In most of these studies, 3,4,6 -8 the prepolymers are crosslinked in bulk state where the effect of so-called trapped entanglement ͑which originates from the uncrossabilities of polymer chains͒ on the elasticity is discussed in terms of the molecular weight (M ) of prepolymer. On the other hand, in the system that the prepolymers with a certain M are crosslinked in solution state, the number of trapped entanglements is governed by the preparation concentration.…”
Section: Introductionmentioning
confidence: 99%
See 1 more Smart Citation
“…[1][2][3][4][5][6][7][8] In most of these studies, 3,4,6 -8 the prepolymers are crosslinked in bulk state where the effect of so-called trapped entanglement ͑which originates from the uncrossabilities of polymer chains͒ on the elasticity is discussed in terms of the molecular weight (M ) of prepolymer. On the other hand, in the system that the prepolymers with a certain M are crosslinked in solution state, the number of trapped entanglements is governed by the preparation concentration.…”
Section: Introductionmentioning
confidence: 99%
“…The interpretation on the effect of trapped entanglements is still in dispute. Some authors have argued that trapped entanglements act similarly as chemical crosslinks, 3,6,8 while others have treated the effect of trapped entanglements only through the restriction on the fluctuations of chemical crosslinks. 4,7,27 In the system crosslinked in solution, the number of trapped entanglements is controlled by 0 .…”
Section: Introductionmentioning
confidence: 99%
“…a linear line, then we can easily get c 1 and c 2 from the intercept and slope [28][29][30], respectively. However, the plot is not exactly a linear line.…”
Section: Mr Model and Determination Of Materials Constantsmentioning
confidence: 99%
“…Fortunately, there are some literatures on for relevant experiments [28][29][30]. In addition, Gent [31] has proposed some other methods to get the material constants.…”
Section: Introductionmentioning
confidence: 99%
“…Therefore, the established theory of rubber elasticity [8,23,24,25] is applicable if the strands are freely fluctuating. At temperatures well above their glass transition, the molecular strands are usually quite mobile.…”
Section: Rubber Elasticitymentioning
confidence: 99%