Radio-frequency-induced plasma copolymerization of acrylic acid=1,7-octadiene was used to produce a range of functionalized plasma copolymer coatings with controlled degree of adhesion. The single-®bre fragmentation test was used to characterize the adhesion of plasma copolymer coated ®bres to epoxy resin. The cumulative stress transfer function (CSTF) and Kelly-Tyson approaches were used to evaluate the degree of adhesion. By continuous monitoring of the fragmentation process, it was found that the mechanical performance of a composite material could be evaluated using the CSTF methodology at strain well below saturation. The degree of debonding was a good measure of relative interface=interphase adhesive strength. The trend in the CSTF is consistent with the propagation of interfacial debonds during the test. For a completely debonded ®bre a normalized CSTF value, referred as stress transfer ef®ciency (STE), was found to provide a more consistent analysis that was able to differentiate between ®bres with similar degrees of debonding. The calculated values of interfacial shear strength (IFSS) were only valid for a fully debonded ®bre (1,7-octadiene plasma homopolymer coating) where the assumption of a constant shear stress, as in the Kelly-Tyson model, applied. However, IFSS did not provide the same ranking. Where debonding does not occur, the stress transfer ef®ciency also provides a sensitive measure of the interface=interphase performance. Improved adhesion over the untreated-unsized carbon ®bre was observed for both of the plasma copolymercoated and commercially treated carbon ®bres. Since there is a concentration dependence of carboxyl groups on adhesion, the mechanism appears to relate to covalent bond formation with the epoxy group. Plasma copolymer coatings on carbon ®bres also causes an increased tensile strength and Weibull modulus.