1998
DOI: 10.1006/jcis.1997.5345
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Streaming Current of Polystyrene Porous Plugs: Solvent Composition Effect

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Cited by 9 publications
(9 citation statements)
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“…This may be attributed to various effects: (i) A dissociation decrease of the functional (sulfate) groups at higher ethanol content, lowering the titrable charge. Such an effect has been reported in previous papers (12,13). (ii) A change in the solvent-solvent interactions due to the addition of ethanol molecules may bring out a decrease in some of the medium properties such as the dielectric constant and the liquid conductivity and, as a consequence of the latter, a decrease in the ionic mobility.…”
Section: Resultsmentioning
confidence: 52%
“…This may be attributed to various effects: (i) A dissociation decrease of the functional (sulfate) groups at higher ethanol content, lowering the titrable charge. Such an effect has been reported in previous papers (12,13). (ii) A change in the solvent-solvent interactions due to the addition of ethanol molecules may bring out a decrease in some of the medium properties such as the dielectric constant and the liquid conductivity and, as a consequence of the latter, a decrease in the ionic mobility.…”
Section: Resultsmentioning
confidence: 52%
“…The mechanism considered here is thus compatible with the experimental results of zeta potential measurements and potentiometric titration. It was evoked moreover, by several authors [20,21]. To confirm the role of ethanol in the distribution of the species in the close vicinity of the surface, other techniques of characterization must be developed, such as the measurements of forces between surfaces by atomic force microscopy.…”
Section: Discussionmentioning
confidence: 98%
“…The streaming current setup was previously described [2]. Before the electric conductivity of the porous plug was determined, the study was focused on the cell (without material).…”
Section: Methodsmentioning
confidence: 99%
“…The porous plugs were prepared via centrifugation, since this is the most successful preparation technique [2,7]. The particle diameter is shown in Table 1.…”
Section: Methodsmentioning
confidence: 99%
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