Stereoselective synthesis of fluorinated materials catalyzed by an antibody

Kitazume, Tomoya; Lin, J. T.; Takeda, Mayu; Yamazaki, Takashi

doi:10.1021/ja00006a032

Cited by 45 publications

(4 citation statements)

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“…Materials. 1,4-Diiodo-2,5-dioctylbenzene (1a), 31 1,4-diiodo-2,5-dioctoxybenzene (1b), 31 p-divinylbenzene, 32 and 4-(diethoxyphosphorylmethyl)benzoic acid methyl ester (4) 41 were prepared according to literature procedures. Tetrahydrofuran (THF) was redistilled from Na + /benzophenone ketyl.…”

Section: Methodsmentioning

confidence: 99%

Syntheses of Oligophenylenevinylenes−Polyisoprene Diblock Copolymers and Their Microphase Separation

Li¹,

Wang²,

Yu³

et al. 1999

Macromolecules

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A series of functionalized oligophenylenevinylene (OPV) molecules have been synthesized via an orthogonal approach for the purpose of preparing diblock copolymers. The coupling reaction between the aldehyde-terminated OPVs and a “living” polyisoprene (PI) species leads to the formation of OPV−PI diblock copolymers. TEM results on thin films of four copolymers with the same OPV block but different lengths of the PI blocks clearly show nanophase separation. Alternating strips of OPV- and PI-rich lamella domains were observed under TEM, confirmed by the SAXS experiments on bulk samples. Temperature-dependent SAXS studies also revealed an order−disorder transition at around 128 °C for copolymer 1, which is consistent with the TEM results.

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Section: Methodsmentioning

confidence: 99%

Syntheses of Oligophenylenevinylenes−Polyisoprene Diblock Copolymers and Their Microphase Separation

Li¹,

Wang²,

Yu³

et al. 1999

Macromolecules

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show abstract

“…4-(Diethoxyphosphorylmethyl)benzoic acid methyl ester [18] and NLO chromophore compound 3 [19] were prepared according to literature procedures. All of the other chemicals were purchased from Aldrich and used as received unless otherwise stated.…”

Section: Methodsmentioning

confidence: 99%

A Multifunctional Photorefractive Material Showing High Optical Gain and Diffraction Efficiency

Gharavi

Wang

et al. 1998

Adv. Mater.

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“…For example, racemates of the fluorine-containing alcohols 19a were resolved by hydrolysis of the corresponding phenylacetates 19b. 21 CA with predetermined stereoselectivity were generated using enantiomers of the hapten 20 having an R-or S-configuration.…”

Section: P O O Ormentioning

confidence: 99%

Catalytic antibodies: prospects for the use in organic synthesis

Kochetkov¹

1998

Russ. Chem. Rev.

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Stereoselective synthesis of fluorinated materials catalyzed by an antibody

Cited by 45 publications

References 0 publications

Syntheses of Oligophenylenevinylenes−Polyisoprene Diblock Copolymers and Their Microphase Separation

Syntheses of Oligophenylenevinylenes−Polyisoprene Diblock Copolymers and Their Microphase Separation

A Multifunctional Photorefractive Material Showing High Optical Gain and Diffraction Efficiency

Catalytic antibodies: prospects for the use in organic synthesis

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