Statistics of Raman-active excitations via measurement of Stokes–anti-Stokes correlations

Abstract

A general fundamental relation connecting the correlation of Stokes and anti-Stokes modes to the quantum statistical behavior of vibration and pump modes in Raman-active materials is derived. We show that under certain conditions this relation can be used to determine the equilibrium number variance of phonons. Time and temperature ranges for which such conditions can be satisfied are studied and found to be available in todays' experimental standards. Furthermore, we examine the results in the presence of multi-mode pump as well as for the coupling of pump to the many vibration modes and discuss their validity in these cases.