Statistical theory for hydrogen bonding fluid system of A&amp;lt;italic&amp;gt;&amp;lt;sub&amp;gt;a&amp;lt;/sub&amp;gt;&amp;lt;/italic&amp;gt;D&amp;lt;italic&amp;gt;&amp;lt;sub&amp;gt;d&amp;lt;/sub&amp;gt;&amp;lt;/italic&amp;gt; type (V): Phase behaviors of fluid in a spherical micro-cavity

顾芳,; 王海军,; 付东,

doi:10.1360/032012-23

Sci. Sin.-Chim

2013

DOI: 10.1360/032012-23

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Statistical theory for hydrogen bonding fluid system of A<italic><sub>a</sub></italic>D<italic><sub>d</sub></italic> type (V): Phase behaviors of fluid in a spherical micro-cavity

顾芳顾芳¹,

王海军王海军²,

付东付东³

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Phase Equilibria of Hydrogen Bonding Fluid in a Slit Pore with Broken Symmetry

Liu

Wang

2015

Chinese Journal of Chemical Physics

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Phase equilibria of hydrogen bonding (HB) fluid confined in a slit pore with broken symmetry were investigated by the density functional theory incorporated with modified fundamental measure theory, where the symmetry breaking originated from the distinct interactions between fluid molecules and two walls of the slit pore. In terms of adsorption-desorption isotherms and the corresponding grand potentials, phase diagrams of HB fluid under various conditions are presented. Furthermore, through phase coexistences of laying transition and capillary condensation, the effects of HB interaction, pore width, fluid-pore interaction and the broken symmetry on the phase equilibrium properties are addressed. It is shown that these factors can give rise to apparent influences on the phase equilibria of confined HB fluid because of the competition between intermolecular interaction and fluid-pore interaction. Interestingly, a significant influence of broken symmetry of the slit pore is found, and thus the symmetry breaking can provide a new way to regulate the phase behavior of various confined fluids.

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Phase Equilibria of Hydrogen Bonding Fluid in a Slit Pore with Broken Symmetry

Liu

Wang

2015

Chinese Journal of Chemical Physics

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View full text Add to dashboard Cite

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Statistical theory for hydrogen bonding fluid system of A<italic><sub>a</sub></italic>D<italic><sub>d</sub></italic> type (V): Phase behaviors of fluid in a spherical micro-cavity

Cited by 1 publication

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Phase Equilibria of Hydrogen Bonding Fluid in a Slit Pore with Broken Symmetry

Phase Equilibria of Hydrogen Bonding Fluid in a Slit Pore with Broken Symmetry

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