Stabilized zirconia-based sensor using oxide electrode for detection of NO  in high-temperature combustion-exhausts

Miura, Norio; Kurosawa, Hideyuki; Hasei, Masaharu; Lu, Geyu; Yamazoe, Noboru

doi:10.1016/0167-2738(96)00252-4

Cited by 173 publications

(79 citation statements)

References 8 publications

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“…Further developments of this type of sensor based on nonNernstian potential using noble metal-based SEs, such as Pt-SE, Mo (or Pt alloy)-SE, catalyst layer/Pt-SE, RuO 2 -SE, and Pt-SE for detection of HCs (or CO), were reported by Moseley and Tofield in 1987 [35], Vogel et al in 1993 [36], Tan et al in 1993 and [37,38], Narducci et al in 1994 [39], and Can et al in 1995 [40], respectively. Moreover, the important improvements in sensing capabilities of the mixed-potential type YSZ-based gas sensors were achieved by [41,42], Miura et al in 1995 [43] and 1996 [44][45][46][47], and Jakobs et al in 1996 [48], by replacing the noble metalbased SEs with inexpensive oxide-SEs. For example, SnO 2 , spinel-type oxides, WO 3 , and ZnO were utilized as SE materials for the mixed-potential type gas sensors to detect reducing gases [41,42], NO x [44,45], H 2 S [43,46], and H 2 [47], respectively.…”

Section: Introductionmentioning

confidence: 99%

“…Moreover, the important improvements in sensing capabilities of the mixed-potential type YSZ-based gas sensors were achieved by [41,42], Miura et al in 1995 [43] and 1996 [44][45][46][47], and Jakobs et al in 1996 [48], by replacing the noble metalbased SEs with inexpensive oxide-SEs. For example, SnO 2 , spinel-type oxides, WO 3 , and ZnO were utilized as SE materials for the mixed-potential type gas sensors to detect reducing gases [41,42], NO x [44,45], H 2 S [43,46], and H 2 [47], respectively. In 1996 and 1997, Sorita and Kawano have also reported the YSZ-based sensor using various mixed oxides (e.g., perovskite and spinel) as SE coated with an Al 2 O 3 (+Pt) catalyst layer for selective detection of CO (or H 2 ) [49,50].…”

Section: Introductionmentioning

confidence: 99%

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A review of mixed-potential type zirconia-based gas sensors

Miura

Sato

Anggraini

et al. 2014

Ionics

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A robust and reliable gas sensing device is considered as a convenient and practical solution for gas concentration monitoring that has become a mandatory requirement in different field of applications. For in situ hazardous gases detection, a mixed-potential type gas sensor has been regarded as a promising solid-state gas sensor. For the past three decades, there has been a significant progress in achieving high performance in mixed-potential type sensors. Therefore, this review is focused on reporting the development of mixedpotential type gas sensors with combined yttria-stabilized zirconia (YSZ) as the base solid electrolyte material and various classes of electrode materials for their potential utilization as a high-performance sensing electrode. The underlying sensing mechanism of a mixed-potential type YSZ-based sensor is elaborated here in detail. Transformation in design and configuration of this type of sensor is also covered in this report. In addition, recent progresses on mixed-potential type gas sensors development for detection of several target gases, such as carbon monoxide, hydrocarbons, nitrogen oxides, hydrogen, and ammonia, are reviewed. Strategies to improve the sensing characteristic, particularly gas sensitivity and selectivity, are also reported. Based on the understanding of the fundamental sensing mechanism and the requirements for high-performance gas sensors, challenges and future trends for this type of gas sensor development are discussed.

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Section: Introductionmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

A review of mixed-potential type zirconia-based gas sensors

Miura

Sato

Anggraini

et al. 2014

Ionics

Self Cite

295

175

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“…According to Mixed Potential Theory [Miura 1996SSI, Miura 1998], the potential difference between a sensing electrode and a reference electrode in a potentiometric sensor is attributed to the redox reactions taking place on both electrodes according to Eqs. 9 and 10.…”

Section: No X Adsorption Discussionmentioning

confidence: 99%

“…al. [Miura 1996 SSI] for a CdMn 2 O 4 spinel metal-oxide sensing electrode with a platinum air reference. Additionally, Brosha et.…”

Section: No X Adsorption Discussionmentioning

confidence: 99%

Hierarchical Nanoceramics for Industrial Process Sensors

Ruud¹,

Brosnan²,

Striker³

et al. 2011

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“…Thus, there is a need for inexpensive and portable sensors in various fields. Although semiconductor gas sensors as well as electrochemical sensors have been developed to determine the concentration of NO, (3)(4)(5)(6)(7) in general, they are poor at distinguishing NO from NO 2 .…”

Section: Introductionmentioning

confidence: 99%

Nitric Oxide Gas Sensors Using Multilayered Thin Film with Interspaces

2018

Sensors and Materials

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Nitric oxide (NO) is an air pollutant known to adversely affect the environment, humans, and other living organisms. Low-level NO gas is also created by human bodies and emitted as a component of exhaled breath and skin gas under some health conditions. Therefore, there is a strong demand for the monitoring of NO gas concentration. In this paper, we present novel NO gas sensors that have been developed using multilayered WO 3 -based thin films with interspaces. Ag doping into a WO 3 thin film is effective in increasing the sensitivity to NO. Multilayered thin-film sensors with interspaces successfully enhance both sensitivity and selectivity to NO. The developed sensor with quadruple-layered sensing films can detect as low as 0.5 ppm NO gas with good selectivity at an operating temperature of 290 ℃. The response and recovery times are 81 and 138 s, respectively, for the double-layered sensor, while its sensitivity is lower than that of the quadruple-layered sensor. Thus, the sensors are promising as a portable and inexpensive NO sensing device in various application fields such as environmental monitoring and health diagnosis.

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Stabilized zirconia-based sensor using oxide electrode for detection of NO in high-temperature combustion-exhausts

Cited by 173 publications

References 8 publications

A review of mixed-potential type zirconia-based gas sensors

A review of mixed-potential type zirconia-based gas sensors

Hierarchical Nanoceramics for Industrial Process Sensors

Nitric Oxide Gas Sensors Using Multilayered Thin Film with Interspaces

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