1998
DOI: 10.1021/ie9703447
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Stabilization of an Unstable Distillation Column

Abstract: Bekiaris et al. (Ind. Eng. Chem. Res. 1993, 32 (9), 2023) explained the existence of multiple steady states in homogeneous azeotropic distillation on the basis of the analysis of columns with infinite reflux and infinite length (infinite number of trays). They showed that the predictions of multiple steady states for such infinite columns have relevant implications for columns of finite length operated at finite reflux. The first experimental verification of the existence of such multiple steady states was pub… Show more

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Cited by 30 publications
(36 citation statements)
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“…There are three steady-state branches: two stable steady-state branches and an unstable branch; this was experimentally verified in an industrial pilot column operated at finite reflux [23,39]. Multiple steady-states can be predicted by analyzing columns with infinite reflux and infinite length [14,38,64].…”
Section: Background Of the Problemmentioning
confidence: 85%
“…There are three steady-state branches: two stable steady-state branches and an unstable branch; this was experimentally verified in an industrial pilot column operated at finite reflux [23,39]. Multiple steady-states can be predicted by analyzing columns with infinite reflux and infinite length [14,38,64].…”
Section: Background Of the Problemmentioning
confidence: 85%
“…In addition, a -20% step change in the boilup results in a stable response with the column settling at a new steady state implying feasibility. These dynamic results serve to highlight that the implementation of feedback control serves to mitigate the non-linear effects of output multiplicity so that an open loop steady transition is prevented (Dorn et al, 1998). Feedback control also ensures feasible operation over a larger disturbance range.…”
Section: Ideal Rd Columnmentioning
confidence: 90%
“…These multiplicities have been verified experimentally for a ternary homogeneous Ž and a heterogeneous system Muller. and Marquardt, 1997;Dorn et al, 1998 . Ž . Note that the forth type 2b only occurs in reactive distil-Ž .…”
Section: žmentioning
confidence: 99%