2013
DOI: 10.1002/adma.201301280
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Spirocyclic Aromatic Hydrocarbon‐Based Organic Nanosheets for Eco‐Friendly Aqueous Processed Thin‐Film Non‐Volatile Memory Devices

Abstract: Supramolecular steric hindrance designs make pyrene-functionalized spiro[fluorene-9,7'-dibenzo[c,h]acridine]-5'-one (Py-SFDBAO) assemble into 2D nanostructures that facilitate aqueous phase large-area synthesis of high-quality and uniform crystalline thin films. Thin-film diodes using aqueous nanosheets as active layers exhibit a non-volatile bistable electrical switching feature with ON/OFF ratios of 6.0 × 10(4) and photoswitching with conductive gains of 10(2) -10(3). Organic nanosheets are potentially key c… Show more

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Cited by 61 publications
(42 citation statements)
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“…At the same time, an urgent ecological issue occurs due to vast amounts of unrecyclable and environmental e‐waste are produced and abandoned annually 13, 14. Pressures arising from the tremendous require amount of data‐storage devices, coupled with a green strategy to solve global environmental problems, have inspired the development of more creative and environmentally friendly solutions 15, 16. In this respect, state‐of‐the‐art, bioinspired resistive random access memory (RRAM) based on biomaterials has been considered as effective strategy to solve the urgent ecological issue stemmed from increased amount of annually abandoned unrecyclable e‐waste 17, 18, 19.…”
mentioning
confidence: 99%
“…At the same time, an urgent ecological issue occurs due to vast amounts of unrecyclable and environmental e‐waste are produced and abandoned annually 13, 14. Pressures arising from the tremendous require amount of data‐storage devices, coupled with a green strategy to solve global environmental problems, have inspired the development of more creative and environmentally friendly solutions 15, 16. In this respect, state‐of‐the‐art, bioinspired resistive random access memory (RRAM) based on biomaterials has been considered as effective strategy to solve the urgent ecological issue stemmed from increased amount of annually abandoned unrecyclable e‐waste 17, 18, 19.…”
mentioning
confidence: 99%
“…Meanwhile, the development of transient memory devices is highly desirable to fulfill the future demands of transient information storage systems . Resistive switching memory is one of the most viable for next generation nonvolatile memories due to its simple structure, low cost, low power consumption, and excellent scalability . Naturally occurring biomaterials, especially proteins, have been found to exhibit resistive switching memory properties .…”
mentioning
confidence: 99%
“…Over the past few years, tremendous efforts have been made in finding the next generation of electrical memory materials that can be employed into memory devices with low switch-threshold voltages (V th ), high ON/OFF current ratios, and high stabilities. [6][7][8][9][10][11][12][13][14] In recent years, electrical memory devices based on small organic molecules have been of considerable interest, owing to their well-confined structures, good stimuli-response, ease of purification, and versatility in molecular design. [15][16][17][18] In 2010, we reported a small-molecule-based ternary-data-storage device based on the charge-trap theory, which may be used to realize the next generation of high-density data storage (HDDS) devices.…”
Section: Introductionmentioning
confidence: 99%