Abstract:Significance
We present a mechanism for unconventional superconductivity in doped band insulators, where short-ranged pairing interaction arises from Coulomb repulsion due to virtual interband or excitonic processes. Remarkably, electron pairing is found upon infinitesimal doping, giving rise to Bose–Einstein condensate (BEC)–Bardeen–Cooper–Schrieffer (BCS) crossover at low density. Our theory explains puzzling behaviors of superconductivity and predicts spin-triplet pairing in electron-… Show more
“…Similar results have also been reported in Bernal bilayer graphene (BBG) [35], and both experimental observations were interpreted theoretically as a signature of spintriplet f -wave pairing [36,37]. More recently, Crépel and Fu proposed that a novel 'three-particle' mechanism involving virtual excitons generically gives rise to spintriplet pairing in a two-valley electron liquid formed in doped insulators such as ZrNCl [38].…”
Section: Introductionsupporting
confidence: 74%
“…The proposed mechanism applies in general to any material with hexagonal symmetry that exhibits gapped f -wave superconductivity in its monolayer form. Here we discuss how the exotic T -broken phase and the non-Abelian excitations can be realized in twisted double layers formed by the two most promising candidate materials, rhombohedral graphene [34,35] and ZrNCl [38], which are thought to be STVS superconductors.…”
Section: Discussionmentioning
confidence: 99%
“…2a). Such Hamiltonians are widely used to model systems with hexagonal symmetry whose FS consist of disconnected segments around K-points [38,42] shown in Fig. 2b.…”
Section: Normal-state Fermiologymentioning
confidence: 99%
“…Motivated by the phenomenology observed in RTG and BBG systems [34,35] and by theoretical ideas introduced in Ref. [38], we focus here on equal-spin pairing between electrons belonging to opposite valleys and drop the spin index in our discussions. Moreover, we consider hole doping near K-points by setting t > 0 with band maxima located at ±K given by E max = 3t in each isolated layer (the case of electron doping can be covered by setting t < 0 with E min = 3t).…”
Section: Normal-state Fermiologymentioning
confidence: 99%
“…While microscopic mechanisms leading to STVS superconductivity may vary across materials such as RTG/BBG [36,37] and ZrNCl [38], on general grounds the interaction responsible for STVS pairing boils down to an effective attraction between electrons in the spintriplet f -wave channel. In the momentum-space representation, the interaction within each isolated layer of STVS superconductor has the form…”
Recent theoretical and experimental studies point to a novel spin-triplet valley-singlet (STVS) superconducting phase in certain two-valley electron liquids, including rhombohedral trilayer graphene, Bernal bilayer graphene and ZrNCl. This fully gapped phase is exotic in that it combines into Cooper pairs same-spin electrons from valleys centered around the opposing corners of a hexagonal Brillouin zone, but is, nevertheless, topologically trivial. Here, we predict that upon stacking two layers of an STVS material with an angular twist, a novel chiral topological phase -an f ± if -wave superconductor -emerges in the vicinity of the 'maximal' twist angle of 30 • where the system becomes an extrinsic quasi-crystal with 12-fold tiling. The resulting composite is a non-Abelian topological superconductor with an odd number of chiral Majorana modes at its edges and a single Majorana zero mode (MZM) localized in the vortex core. As the twist angle deviates from 30 • , the system generically becomes a nodal f -wave topological superconductor supporting non-dispersive MZMs on the edge. Through symmetry analysis and detailed microscopic modelling based on a novel quasi-crystal band structure technique, we demonstrate that the chiral phase forms when the isolated Fermi pockets coalesce into a single connected Fermi surface around the center of the moiré Brillouin zone and is stable over a wide range of electron density. Our results thus establish a new platform for realizing, through twist angle engineering, an intrinsic chiral topological superconductor with non-Abelian excitations.
“…Similar results have also been reported in Bernal bilayer graphene (BBG) [35], and both experimental observations were interpreted theoretically as a signature of spintriplet f -wave pairing [36,37]. More recently, Crépel and Fu proposed that a novel 'three-particle' mechanism involving virtual excitons generically gives rise to spintriplet pairing in a two-valley electron liquid formed in doped insulators such as ZrNCl [38].…”
Section: Introductionsupporting
confidence: 74%
“…The proposed mechanism applies in general to any material with hexagonal symmetry that exhibits gapped f -wave superconductivity in its monolayer form. Here we discuss how the exotic T -broken phase and the non-Abelian excitations can be realized in twisted double layers formed by the two most promising candidate materials, rhombohedral graphene [34,35] and ZrNCl [38], which are thought to be STVS superconductors.…”
Section: Discussionmentioning
confidence: 99%
“…2a). Such Hamiltonians are widely used to model systems with hexagonal symmetry whose FS consist of disconnected segments around K-points [38,42] shown in Fig. 2b.…”
Section: Normal-state Fermiologymentioning
confidence: 99%
“…Motivated by the phenomenology observed in RTG and BBG systems [34,35] and by theoretical ideas introduced in Ref. [38], we focus here on equal-spin pairing between electrons belonging to opposite valleys and drop the spin index in our discussions. Moreover, we consider hole doping near K-points by setting t > 0 with band maxima located at ±K given by E max = 3t in each isolated layer (the case of electron doping can be covered by setting t < 0 with E min = 3t).…”
Section: Normal-state Fermiologymentioning
confidence: 99%
“…While microscopic mechanisms leading to STVS superconductivity may vary across materials such as RTG/BBG [36,37] and ZrNCl [38], on general grounds the interaction responsible for STVS pairing boils down to an effective attraction between electrons in the spintriplet f -wave channel. In the momentum-space representation, the interaction within each isolated layer of STVS superconductor has the form…”
Recent theoretical and experimental studies point to a novel spin-triplet valley-singlet (STVS) superconducting phase in certain two-valley electron liquids, including rhombohedral trilayer graphene, Bernal bilayer graphene and ZrNCl. This fully gapped phase is exotic in that it combines into Cooper pairs same-spin electrons from valleys centered around the opposing corners of a hexagonal Brillouin zone, but is, nevertheless, topologically trivial. Here, we predict that upon stacking two layers of an STVS material with an angular twist, a novel chiral topological phase -an f ± if -wave superconductor -emerges in the vicinity of the 'maximal' twist angle of 30 • where the system becomes an extrinsic quasi-crystal with 12-fold tiling. The resulting composite is a non-Abelian topological superconductor with an odd number of chiral Majorana modes at its edges and a single Majorana zero mode (MZM) localized in the vortex core. As the twist angle deviates from 30 • , the system generically becomes a nodal f -wave topological superconductor supporting non-dispersive MZMs on the edge. Through symmetry analysis and detailed microscopic modelling based on a novel quasi-crystal band structure technique, we demonstrate that the chiral phase forms when the isolated Fermi pockets coalesce into a single connected Fermi surface around the center of the moiré Brillouin zone and is stable over a wide range of electron density. Our results thus establish a new platform for realizing, through twist angle engineering, an intrinsic chiral topological superconductor with non-Abelian excitations.
Coulomb interactions among electrons and holes in 2D semimetals with overlapping valence and conduction bands can give rise to a correlated insulating ground state via exciton formation and condensation. One candidate material in which such excitonic state uniquely combines with non‐trivial band topology are atomic monolayers of tungsten ditelluride (WTe2), in which a 2D topological excitonic insulator (2D TEI) forms. However, the detailed mechanism of the 2D bulk gap formation in WTe2, in particular with regard to the role of Coulomb interactions, has remained a subject of ongoing debate. Here, it shows that WTe2 is susceptible to a gate‐tunable quantum phase transition, evident from an abrupt collapse of its 2D bulk energy gap upon ambipolar field‐effect doping. Such gate tunability of a 2D TEI, into either n‐ and p‐type semimetals, promises novel handles of control over non‐trivial 2D superconductivity with excitonic pairing.
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