Developing new materials and novel
technologies for the highly
efficient treatment of toxic organic pollutants is highly desirable.
Chemical reduction based on heterogeneous substrate/noble metal catalysts
and the reducing agent NaBH4 has become an effective method
in recent years. Here, a spherical covalent organic framework (SCOF)
was designed to provide basic sites for Ag ions, by which small Ag
NPs were immobilized on the SCOF to form Ag NPs@SCOF microspheres.
The prepared microspheres exhibited a high catalytic reduction ability
toward 4-nitrophenol (4-NP). An optimized permeation flux of 2000
L m–2 h–1 (LMH) and a more than
99% 4-NP reduction efficiency were obtained with flow-through experiments,
which are far better than the reported results (below 200 LMH). Moreover,
the microspheres could maintain stable catalytic performance under
a continuous flow-through process. Our work provides an efficient
material and technology that can be applied to easily treat toxic
organic pollutants.