The application of polymer solar cells requires the realization of high efficiency, high stability, and low cost devices. Here we demonstrate a low-cost polymer donor poly[(thiophene)-alt-(6,7-difluoro-2-(2-hexyldecyloxy)quinoxaline)] (PTQ10), which is synthesized with high overall yield of 87.4% via only two-step reactions from cheap raw materials. More importantly, an impressive efficiency of 12.70% is obtained for the devices with PTQ10 as donor, and the efficiency of the inverted structured PTQ10-based device also reaches 12.13% (certificated to be 12.0%). Furthermore, the as-cast devices also demonstrate a high efficiency of 10.41% and the devices exhibit insensitivity of active layer thickness from 100 nm to 300 nm, which is conductive to the large area fabrication of the devices. In considering the advantages of low cost and high efficiency with thickness insensitivity, we believe that PTQ10 will be a promising polymer donor for commercial application of polymer solar cells.
Achieving efficient charge transfer at small frontier molecular orbital offsets between donor and acceptor is crucial for high performance polymer solar cells (PSCs). Here we synthesize a new wide band gap polymer donor, PTQ11, and a new low band gap acceptor, TPT10, and report a high power conversion efficiency (PCE) PSC (PCE = 16.32%) based on PTQ11–TPT10 with zero HOMO (the highest occupied molecular orbital) offset (ΔE HOMO(D–A)). TPT10 is a derivative of Y6 with monobromine instead of bifluorine substitution, and possesses upshifted lowest unoccupied molecular orbital energy level (E LUMO) of −3.99 eV and E HOMO of −5.52 eV than Y6. PTQ11 is a derivative of low cost polymer donor PTQ10 with methyl substituent on its quinoxaline unit and shows upshifted E HOMO of −5.52 eV, stronger molecular crystallization, and better hole transport capability in comparison with PTQ10. The PSC based on PTQ11–TPT10 shows highly efficient exciton dissociation and hole transfer, so that it demonstrates a high PCE of 16.32% with a higher V oc of 0.88 V, a large J sc of 24.79 mA cm–2, and a high FF of 74.8%, despite the zero ΔE HOMO(D–A) value between donor PTQ11 and acceptor TPT10. The PCE of 16.32% is one of the highest efficiencies in the PSCs. The results prove the feasibility of efficient hole transfer and high efficiency for the PSCs with zero ΔE HOMO(D–A), which is highly valuable for understanding the charge transfer process and achieving high PCE of PSCs.
Na 3 V 2 (PO 4 ) 3 (denoted as NVP) has been considered as a promising cathode material for room temperature sodium ion batteries. Nevertheless, NVP suffers from poor rate capability resulting from the low electronic conductivity. Here, the feasibility to approach high rate capability by designing carbon-coated NVP nanoparticles confi ned into highly ordered mesoporous carbon CMK-3 matrix (NVP@C@CMK-3) is reported. The NVP@C@CMK-3 is prepared by a simple nanocasting technique. The electrode exhibits superior rate capability and ultralong cyclability (78 mA h g −1 at 5 C after 2000 cycles) compared to carbon-coated NVP and pure NVP cathode. The improved electrochemical performance is attributed to double carbon coating design that combines a variety of advantages: very short diffusion length of Na + /e − in NVP, easy access of electrolyte, and short transport path of Na + through carbon toward the NVP nanoparticle, high conductivity transport of electrons through the 3D interconnected channels of carbon host. The optimum design of the core-shell nanostructures with double carbon coating permits fast kinetics for both transported Na + ions and electrons, enabling high-power performance.
The application of polymer solar cells (PSCs) with n-type organic semiconductor as acceptor requires further improving powder conversion efficiency, increasing stability and decreasing cost of the related materials and devices. Here we report a simplified synthetic route for 4,4,9,9-tetrahexyl-4,9-dihydro-s-indaceno [1,2-b:5,6-b’] dithiophene by using the catalyst of amberlyst15. Based on this synthetic route and methoxy substitution, two low cost acceptors with less synthetic steps, simple post-treatment and high yield were synthesized. In addition, the methoxy substitution improves both yield and efficiency. The high efficiency of 13.46% was obtained for the devices with MO-IDIC-2F (3,9-bis(2-methylene-5 or 6-fluoro-(3-(1,1-dicyanomethylene)-indanone)-4,4,9,9-tetrahexyl-5,10-dimethoxyl-4,9-dihydro-s-indaceno[1,2-b:5,6-b’] dithiophene) as acceptor. Based on the cost analysis, the PSCs based on MO-IDIC-2F possess the great advantages of low cost and high photovoltaic performance in comparison with those PSCs reported in literatures. Therefore, MO-IDIC-2F will be a promising low cost acceptor for commercial application of PSCs.
Four low‐cost copolymer donors of poly(thiophene‐quinoxaline) (PTQ) derivatives are demonstrated with different fluorine substitution forms to investigate the effect of fluorination forms on charge separation and voltage loss (Vloss) of the polymer solar cells (PSCs) with the PTQ derivatives as donor and a A–DA'D–A‐structured molecule Y6 as acceptor. The four PTQ derivatives are PTQ7 without fluorination, PTQ8 with bifluorine substituents on its thiophene D‐unit, PTQ9, and PTQ10 with monofluorine and bifluorine substituents on their quinoxaline A‐unit respectively. The PTQ8‐ based PSC demonstrates a low power conversion efficiency (PCE) of 0.90% due to the mismatch in the highest occupied molecular orbital (HOMO) energy levels alignment between the donor and acceptor. In contrast, the devices based on PTQ9 and PTQ10 show enhanced charge‐separation behavior and gradually reduced Vloss, due to the gradually reduced nonradiative recombination loss in comparison with the PTQ7‐based device. As a result, the PTQ10‐based PSC demonstrates an impressive PCE of 16.21% with high open‐circuit voltage and large short‐circuit current density simultaneously, and its Vloss is reduced to 0.549 V. The results indicate that rational fluorination of the polymer donors is a feasible method to achieve fast charge separation and low Vloss simultaneously in the PSCs.
Flexible and free-standing sulphur/(PCNFs-CNT) composite (S@PCNFs-CNT) electrode was successfully prepared by infiltrating sulfur into microporous carbon nanofibers-carbon nanotube (PCNFs-CNT) composite. When used as a cathode material for Li-S batteries, the S@PCNFs-CNT exhibits much better cycle performance and rate performance compared to CNT-free S@PCNFs. It delivers a reversible capacity of 637 mA h g(-1) after 100 cycles at 50 mA g(-1) and a rate capability of 437 mA h g(-1) at 1 A g(-1). The improved electrochemical performance is attributed to synergistic effect of the 3D interconnected structure, the additive of CNT, and the uniform distribution of micropores (<2 nm) in the PCNFs-CNT matrix. Our results indicate the potential suitability of PCNFs-CNT for efficient, free-standing, and high-performance batteries.
as low-cost solution-processing, lightweight, and easy fabrication of flexible and semitransparent devices. [1][2][3][4][5][6] The device efficiencies have been continuously increasing in the last two decades, [7][8][9] enabled by crosscollaboration among material scientists, physicists, and device specialists; featured material synthesis (especially for nonfullerene acceptors (NFAs), [7,[10][11][12][13][14][15][16] ) optimized BHJ blend processing; [17,18] and detailed understanding on the physical mechanisms. [19][20][21][22][23][24] Very recently, benefiting from the new NFA material synthesis, the power conversion efficiency (PCEs) over 16% in binary solar cells have been realized, [25][26][27][28] which make the solution-processed BHJ PSCs viable for practical applications in the near future.In the active layers, the BHJ morphology architecture helps the photogenerated excitons to dissociate into charge carriers at the D/A interfaces. [29,30] The free carriers diffuse/drift by the built-in electric field and can be further collected at the relevant electrodes via a continuous network of D/A materials. In the process of converting photons to a flow of electricity, efficient charge generation, fast charge carrier extraction, and less carrier recombination loss are prerequisites for realizing high performance devices. [31] However, the requirements of these three competitors (including charge generation, carrier recombination, and extraction) with regard to the interface area of the D/A (morphology) and the active layer thickness are conflicting on the one hand. [32] On the other hand, the optoelectronic properties of the D/A materials, the processing conditions, and the device structures can also greatly determine the properties of the three competitors, which in turn affect device performance. [24,31,33] Thus, finding an effective strategy or approach for simultaneously facilitate charge generation, accelerate carrier extraction, and hinder carrier recombination is very important to further improve device performance.In the organic semiconductors, the excitons of many semiconducting polymers have lifetimes in the range of 10-100 ps, [34] and the relevant diffusion lengths of 5-10 nm, [35] which generally constrain the D/A domain sizes and layer thickness in the active layers. As expected, the above-mentioned three competitors are seriously sensitive to the interface area of the nanoscale morphology, the D/A domain size, and the active layer thickness in BHJs. Many studies demonstrated that photovoltaic materials incorporated with a small amount of complexes or components can improve the relevant blend morphology and photovoltaic performance, especiallyThe commercially available PM6 as donor materials are used widely in highly efficient nonfullerene polymer solar cells (PSCs). In this work, different concentrations of iridium (Ir) complexes (0, 0.5, 1, 2.5, and 5 mol%) are incorporated carefully into the polymer conjugated backbone of PM6 (PM6-Ir0), and a set of π-conjugated polymer donors (named PM6-Ir0.5, PM...
Solution-processable n-doped graphene-containing cathode interfacial material with a low work function demonstrates 16.52% power conversion efficiency in organic solar cells.
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