Spectrophotometric determination of vanadium with 4-(2-pyridylazo) resorcinol

好雄, 四條; 次夫, 武内

doi:10.2116/bunsekikagaku.14.115

Cited by 22 publications

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“…The composition of the complex was estimated by the molar ratio method and was shown to be 1:1 (vanadium to Nitro-PAPS)_ The same 1:1 composition has been reported for vanadium complexes of similar pyridylazobenzene compounds [13][14][15].…”

Section: Characteristics Of Nitro-paps Complex With Vanadium(v)supporting

confidence: 61%

“…The molar absorptivity was calculated from the results in a static experimental system (batchwise measurements after reaching equilibrium). This molar absorptivity is 1.5~2 times larger than that of the vanadium complex of similar pyridylazo compounds like 4-(2-pyridylazo)resorcinol (e = 3.5 x 104) [13,14], 2-(3,5-dibromo-2-pyridylazo)-5-diethylaminophenol (e=5xl04) [2], and 2-(5-bromo-2-pyridylazo)-5-(N-propyl-N-sulphopropylamino)phenol (r = 5.47 x 104) [15] which have been evaluated as sensitive and useful chromogenic reagents for vanadium so far. Thus it can be said that Nitro-PAPS ranks as one of the most sensitive chromogenic reagents known for V(V).…”

Section: Characteristics Of Nitro-paps Complex With Vanadium(v)mentioning

confidence: 81%

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2-(5-Nitro-2-Pyridylazo)-5-(N-Propyl-N-Sulfopropylamino)Phenol as a new analytical reagent for flow-injection spectrophotometric determination of trace vanadium(V)

Yamane

Yamaguchi

1998

Mikrochim Acta

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Abstract.A flow injection method using 2-(5-nitro-2-pyridylazo)-5-(N-propyl-N-sulfopropylamino)phenol-(Nitro-PAPS) as a new chromogenic reagent is presented for sensitive and rapid determination of vanadium. Nitro-PAPS reacts with vanadium(V) in weakly acidic medium to form a water soluble complex of molar absorptivity of 8.0 x 104L mo1-1 cm -~ at 592nm (maximum absorption wavelength), which permits the straightforward application of a flow injection system to the sensitive determination of vanadium. Under the optimum conditions established, a linear calibration graph was obtained in the range 1-120 ng mL -1 . The relative standard deviation for 60ngmL -I vanadium was 2.2% (n= 5) and the limit of detection was 1 ng mL -1. The sample throughput is about 40 h-1. Most inorganic and organic anions examined did not interfere even at concentrations of 3000-6000 times of vanadium. Interference from cobalt(II), copper(II) and nickel(II) at 200ngmL -1 levels can be overcome by the addition of N-(dithiocarboxy)sarcosine. The recoveries for each 20 and 10ngmL -t vanadium added to the river water were 98 and 97%, respectively.Key words: Nitro-PAPS, vanadium, spectrophotometry, FlA.It has been shown that heterocyclic azoderivatives provide highly sensitive chromogenic reagents for some heavy metals which form complexes having molar absorptivities approaching to 105L mol -I cm -1 [1-6]. 2-(5-Nitro-2-pyridylazo)-5-(N-propyl-N-sulfo-* To whom correspondence should be addressed propylamino)phenol(Nitro-PAPS) is a recently synthesized chromogenic reagent giving complexes of high molar absorptivity with metals and good water solubility of both the reagent and its metal complexes [7]. Water solubility of the reagent and its metal complex is one of the important requirements for its use in flow-injection analysis (FIA) which is a rapidly growing analytical technique. Despite of expectable high analytical potential, analytical studies using the Nitro-PAPS have been found only for zinc [8], copper [9] and iron [10,11] determinations to date. Recently we have studied the Nitro-PAPS applied to sensitive post-column reaction detection in ion chromatography of cadmium, lead, and manganese [12]. In addition, we have found that Nitro-PAPS forms a water soluble complex of molar absorptivity of 8.0• 104L mo1-1 cm -1 with vanadium in weak acidic media and thus has potential usefulness to be applied for spectrophotometric determination of vanadium in a FIA system. In the present work, potential analytical significance of such complex formation of Nitro-PAPS with vanadium was studied in detail and a FIA method based on its use is described for the determination of trace vanadium. It has been assumed that Nitro-PAPS ranks as one of the most sensitive chromogenic reagents known for V(V). Experimental Reagents and SolutionsUnless otherwise noted, all reagents were of analytical grade and were used as received. Nitro-PAPS stock solution (1.0x t0 3 M) was prepared by dissolving the reagent (Dojindo, Kumamoto) in

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Section: Characteristics Of Nitro-paps Complex With Vanadium(v)supporting

confidence: 61%

Section: Characteristics Of Nitro-paps Complex With Vanadium(v)mentioning

confidence: 81%

2-(5-Nitro-2-Pyridylazo)-5-(N-Propyl-N-Sulfopropylamino)Phenol as a new analytical reagent for flow-injection spectrophotometric determination of trace vanadium(V)

Yamane

Yamaguchi

1998

Mikrochim Acta

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“…Vanadium(V) reacts with 4-(2-pyridylazo)resorcinol (PAR) producing intensely colored water-soluble anionic complexes (1)(2)(3)(4)(5)(6)(7), which serves as a basis for the spectrophotometric determination of vanadium. The extraction of [4-(2-pyridylazo)resorcinolatojvanadium(V) (V02L") anionic complex paired with quaternary ammonium cations like tetraphenylphosphonium chloride, tetraphenylarsonium chloride, tetradecyldimethylbenzylammonium chloride, trioctylmethylammonium chloride, and with trioctylphosphine oxide has been ivestigated by several workers (8-12).…”

Section: Literature Citedmentioning

confidence: 99%

Extractive spectrophotometric method for the determination of vanadium(V) in steels and titanium base alloy

Yerramilli¹,

Kavipurapu²,

Manda³

et al. 1986

Anal. Chem.

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“…Molybdovanadophosphate was used to determine vanadium after solvent extraction (326) and in low alloy steel (102). The use of 4-(2-pyridylazo)resorcinol as a spectrophotometric reagent for vanadium was described in several papers (13, 131, 635, 358,690,697). Very small amounts of vanadium were determined by spectrophotometric measurement of a boras bead ( 5 ) .…”

Section: Vanadiummentioning

confidence: 99%

“…Very small amounts of vanadium were determined by spectrophotometric measurement of a borax bead (5). The use of 4-(2-pyridylazo)resorcinol as a spectrophotometric reagent for vanadium was described in several papers (13,131,235,358,690,697). A mixed complex of 4-(2-pyridylazo)-resorcinol and hydrogen peroxide with vanadium was also used (689).…”

Section: Zirconium and Hafniummentioning

confidence: 99%

Nonferrous metallurgy. II. Zirconium, hafnium, vanadium, niobium, tantalum, chromium, molybdenum, and tungsten

Bachman¹,

Banks²

1969

Anal. Chem.

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HIS REVIEW, as did the previous two Alizarin red S: ceramic materials (387); alkali hydroxides (253); Zr-Ni alloys (692) Pyrocatechol violet: steel (733); HpSO4 solution (787, 799 Zirconin (Gallocyanine MS) : hlg, Al, Ni, Cu (613); Nb, Mo, Fe, Sn, Ti (516) Stilbazogall 11: study of complex (154): Me: (616) study of complex (515); Chromeaxurol S: stidy of cchditions'(302)-' Chloranilic acid: study of conditions (336) Methylthymol blue: study of complex (751) Chlorosulfophenol S: study of conditions (665) p-Chloromandelic acid: study of conditions (381 ); Phenylfluorone: Ta (628) Robinetin: study of conditions (355) Alberon: Cu (514) Thorin: study of conditions (658) n'-methylanabasine-a'-azoresorcinol : study of conditions N-methylanabasine-a'-azc-p-naphthol: study of condi-3',4',7,RTetrahydroxyflavonol: study of conditions Cyanoformazan-2: study of conditions (421) N-phenylbenzohydroxamic acid: Nb (688) Molybdosulfatozirconic acid: study of conditions (273) 3',4',5',6'-Tetrahydroxyfluoran: study of reactions (604) 1,l'-Dihydroxyazo dyes: study of reactions (394) Azo dyes: comparison of reagents (396) Review of spectrophotometric methods (286, 567, 646, H202: Ti (753); iron ore (163) Molybdovanadophosphate: study of conditions (386), Phosphovanadotungstate: A1 (388), TiC14 (754), coal Borax bead: study of method ( 5 ) 4-(2-Pyridylazo)-resorcinol: study of conditions and interferences (13, 131, 236, 358, 690), crude oil (697) 4-(2-Pyridylazo)-resorcinol-HzOz: study of complex (689) Xylenol orange: study of complex (14, 18, @I), water Methylthymol blue: study of complex (761); Ti (752) Chrome azurol S: study of complex and interferences VOL. 41, NO. 5, APRIL 1969 1 1 3 RTable 1. Spectrophotometric Methods (Cont'd.)Vanadium (Cont'd.) N-(o-tolyl)-benzohydroxamic acid: study of conditions Element Reagent: Material (References) and interferences (467); silirate rocks (332) Salicylhydroxamic acid: biological materials (428) N-Phenylcinnamohydroxamic acid: Fe, U (812) 'V-Phenyl-2-furohydroxamic acid: brines (583); steels N-Phenyl-p-phenylazobenzohydroxamic acid: study of Caprohydroxamic acid: study of conditions (602) Arsenazo I: stitdy of Conditions (457) Gossipol: study of conditions and interferences (363) hlorin: study of conditions and interferences (390) Ferron: ores (469) Azoxine S: study of conditions and interferences (261) Thenoyltrifliioroacetone: study of conditions (311) Cyanoformazan-2 : ore concentrate (819); heat-resistant Formazon : Ti concentrate (41 1 ) Srilfosalicyclic acid: study of conditions and interferences Salicylaldehyde: study of conditions and interferences Salicylaldehyde-anthranilic acid: steel (62) Nicotinic acid hydrazide: study of conditions (412) p-Anisidine: study of conditions and interferences 3-Hydroxyflavone: study of extractants (391) Pyridine-2,6-dicarboxylic acid-Ht02: study of conditions Element Reagent: Material (References) Niobium (Cont'd.) Tantalum Chromium Molybdoniobophosphate: NblO; (809); A1 (388); steel Chlorosulfophenol S: study of complex (115, 666) Cyanoformazan-2:...

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Spectrophotometric determination of vanadium with 4-(2-pyridylazo) resorcinol

Cited by 22 publications

References 0 publications

2-(5-Nitro-2-Pyridylazo)-5-(N-Propyl-N-Sulfopropylamino)Phenol as a new analytical reagent for flow-injection spectrophotometric determination of trace vanadium(V)

2-(5-Nitro-2-Pyridylazo)-5-(N-Propyl-N-Sulfopropylamino)Phenol as a new analytical reagent for flow-injection spectrophotometric determination of trace vanadium(V)

Extractive spectrophotometric method for the determination of vanadium(V) in steels and titanium base alloy

Nonferrous metallurgy. II. Zirconium, hafnium, vanadium, niobium, tantalum, chromium, molybdenum, and tungsten

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