Spectrophometric determination of piperazine with chloranil

Wahbi, Abdel‐Aziz M.; Abounassif, Mohammad; Kariem, Elrasheed A. Gad

doi:10.1039/an9840901513

Cited by 3 publications

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“…A calculated limit of detection (LOD) down to 0.76 µ M and 0.33 µ M is obtained from the spectrophotometric and spectrofluorometric data, respectively, with a linear dynamic range up to 10 μM (Figures 6 and 7). These values are better than those reported in the literature using spectrophotometric methods [63][64][65][66]. Various other techniques have been developed for the detection and quantitation of piperazine, such as HPLC [67], voltammetry [68], or capillary electrophoresis [69]; most of them, however, require time-consuming procedures.…”

Section: Sensing Piperazinementioning

confidence: 84%

Binding Properties of a Dinuclear Zinc(II) Salen-Type Molecular Tweezer with a Flexible Spacer in the Formation of Lewis Acid-Base Adducts with Diamines

et al. 2021

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In this paper we report the binding properties, by combined 1H NMR, optical absorption, and fluorescence studies, of a molecular tweezer composed of two Zn(salen)-type Schiff-base units connected by a flexible spacer, towards a series of ditopic diamines having a strong Lewis basicity, with different chain length and rigidity. Except for the 1,2-diaminoethane, in all other cases the formation of stable 1:1 Lewis acid-base adducts with large binding constants is demonstrated. For α,ω-aliphatic diamines, binding constants progressively increase with the increasing length of the alkyl chain, thanks to the flexible nature of the spacer and the parallel decreased conformational strain upon binding. Stable adducts are also found even for short diamines with rigid molecular structures. Given their preorganized structure, these latter species are not subjected to loss of degrees of freedom. The binding characteristics of the tweezer have been exploited for the colorimetric and fluorometric selective and sensitive detection of piperazine.

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