A fast and direct colorimetric/fluorometric selective sensing of biogenic amines by means of a molecular tweezer.

This paper reports the synthesis and the deaggregation properties of a Lewis acidic Zn(II) salen-type Schiff-base complex derivative from the diaminomaleonitrile, and a systematic detailed study in solution on its...

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The search for feasible and efficient methods for sensing cations in the environment is a challenge of current scientific interest. Among colorimetric and fluorometric methods, those allowing a direct and...

In this paper we report the binding properties, by combined 1H NMR, optical absorption, and fluorescence studies, of a molecular tweezer composed of two Zn(salen)-type Schiff-base units connected by a flexible spacer, towards a series of ditopic diamines having a strong Lewis basicity, with different chain length and rigidity. Except for the 1,2-diaminoethane, in all other cases the formation of stable 1:1 Lewis acid-base adducts with large binding constants is demonstrated. For α,ω-aliphatic diamines, binding constants progressively increase with the increasing length of the alkyl chain, thanks to the flexible nature of the spacer and the parallel decreased conformational strain upon binding. Stable adducts are also found even for short diamines with rigid molecular structures. Given their preorganized structure, these latter species are not subjected to loss of degrees of freedom. The binding characteristics of the tweezer have been exploited for the colorimetric and fluorometric selective and sensitive detection of piperazine.