“…All these values are substantially higher than those obtained for pure argon (2580 K) and helium (1990 K) plasmas with solution nebulization. Moreover, these values are higher than those reported for argon MIP for different microwave devices (surfatron: 2570 K, 8 TE 101 : 2500-2750 K, 26 MPT: 3600 K 27 ). The rotational temperatures obtained at low helium content in mixed-gas plasma are also higher than those for argon ICP with solution nebulization (3340-3500 K) 28,29 and for argon MIP with hydride generation (3740 K).…”
Section: Influence Of Helium Concentration On Ar + He Mip Parameterscontrasting
“…All these values are substantially higher than those obtained for pure argon (2580 K) and helium (1990 K) plasmas with solution nebulization. Moreover, these values are higher than those reported for argon MIP for different microwave devices (surfatron: 2570 K, 8 TE 101 : 2500-2750 K, 26 MPT: 3600 K 27 ). The rotational temperatures obtained at low helium content in mixed-gas plasma are also higher than those for argon ICP with solution nebulization (3340-3500 K) 28,29 and for argon MIP with hydride generation (3740 K).…”
Section: Influence Of Helium Concentration On Ar + He Mip Parameterscontrasting
“…Instead, a variety of mathematical algorithms to fit the raw data and to perform the inversion are employed [9][10][11][12][13][14][15][16]. In the present study, the Nestor-Olsen method was chosen due to its easy computation and widespread use [5,26,28]. In this method, the lateral profile, I(x), is assumed to have axial symmetry with a total of 2N + 1 equally spaced data points.…”
“…This excitation temperature and the OH rotational temperature were both calculated from Boltzmann plots of a collection of lines. 22,23 For OH, the lines were at 308. In both cases, the averages of peak areas from five spectra acquired by scanning the monochromator wavelength were used in the calculations.…”
Use of an electrolyte-cathode glow discharge (ELCAD) with complex samples is explored. The present state of knowledge in this regard is briefly reviewed and several previously undocumented effects are examined. Remedies to various interferences are proposed and evaluated. The implications of the results to the mechanistic understanding of ELCAD are discussed.
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