“…Resistive switching has been commonly observed in various oxides, e.g., Cu x O, 1 NiO, 2,3 TiO 2 , 4-6 SrTiO 3 , 7-9 BaTiO 3 , 10 ͑Ba, Sr͒TiO 3 , 11 SrZrO 3 , 12 La 1−x Sr x MnO 3 , 13 and Pr 1−x Ca x MnO 3 , [14][15][16] as well as in higher chalcogenides, e.g., Ag or Cu doped Ge x Se 1−x , 17,18 Ag 2 S, 19 and Cu 2 S. 20 Quite diverse switching mechanisms have been proposed, based on thermal, electronic, and/or electrochemical effects. In particular, when one involved electrode metal is situated in the intermediate range of the electrochemical potential series and forms mobile cations, such as Ag + and Cu + , bipolar switching characteristics are observed, and electrochemical redox processes are generally accepted to be responsible for the switching.…”