We present a scheme for achieving thermal bistability based on the selective coupling of three optical resonances. This approach requires one of the resonant frequencies to be temperature dependent, which can occur in materials exhibiting strong thermo-optic effects. For illustration, we explore thermal bistability in two different passive systems, involving either a periodic array of Si ring resonators or parallel GaAs thin films separated by vacuum and exchanging heat in the near field. Such a scheme could prove useful for thermal memory devices operating with transition times hundreds of milliseconds.Rapid progress in the synthesis and processing of materials at small lengthscales has created demand for understanding thermal phenomena in nanoscale systems. 1,2 Recent interest in harnessing excess heat that is readily available at the nanoscale has culminated in several proposed thermal devices 3 with various functionalities, including thermal rectifiers, 4 thermal memory, 5 thermal transistors, 6 phononic logic gates, 7 and phonon waveguides. 8 . In this paper, we propose a scheme to achieve thermal bistability based on the coupling between three or more optical resonances. Our approach complements and builds on recently proposed ideas 5,9-11 in several ways, described further below.A thermal, bistable system can be used as a memory device that stores thermal information by maintaining the temperature of the system in one of two or more possible states. Realizing such temperature bistability requires a nonequilibrium thermal circuit supporting multiple steady states. Such a circuit was first proposed several years ago based on the concept of negative differential thermal resistance (NDTR), which relies on the ability to achieve heat flux rates between objects that decrease with increasing temperature differences. While first proposed in a model system consisting of a lattice of one-dimensional nonlinear mechanical oscillators, 5 recent implementations of NDTR have instead sought to exploit radiative energy transfer between slabs separated by nanometer gaps and heated to very high ≈ 1500K temperatures. 11,12 . Here, we propose a simple and experimentally feasible, all-optical scheme based on a system of three optical resonances that builds and expands on a recently proposed and related scheme which requires materials supporting metal-insulator phase-transitions. 9,10 Instead, our approach exploits common materials exhibiting strong thermo-optic effects and relies instead on thermal bistability induced by a resonant mechanism involving three optical resonances-microring cavities supporting travelling-wave resonances or polar-dielectric slabs supporting surface-propagating polaritonic resonances. This work extends previous studies of thermal rectification 4,13 and NDTR through vacuum 11 and also parallels recent ideas based on exotic non-volatile memory systems, 12,14,15 which have recently been proposed as viable alternatives to traditional electrostatic memory. 16,17 Thermal bistability in triply resonant stru...