Soot Oxidation in a Plasma-Catalytic Reactor: A Case Study of Zeolite-Supported Vanadium Catalysts

Abstract

The plasma-catalytic oxidation of soot was studied over zeolite-supported vanadium catalysts, while four types of zeolites (MCM-41, mordenite, USY and 5A) were used as catalyst supports. The soot oxidation rate followed the order of V/MCM-41 > V/mordenite > V/USY > V/5A, while 100% soot oxidation was achieved at 54th min of reaction over V/MCM-41 and V/mordenite. The CO2 selectivity of the process follows the opposite order of oxidation rate over the V/M catalyst. A wide range of catalyst characterizations including N2 adsorption–desorption, XRD, XPS, H2-TPR and O2-TPD were performed to obtain insights regarding the reaction mechanisms of soot oxidation in plasma-catalytic systems. The redox properties were recognized to be crucial for the soot oxidation process. The effects of discharge power, gas flow rate and reaction temperature on soot oxidation were also investigated. The results showed that higher discharge power, higher gas flow rate and lower reaction temperature were beneficial for soot oxidation rate. However, these factors would impose a negative effect on CO2 selectivity. The proposed “plasma-catalysis” method possessed the unique advantages of quick response, mild operation conditions and system compactness. The method could be potentially applied for the regeneration of diesel particulate filters (DPF) at low temperatures and contribute to the the emission control of diesel engines.

Structure-Sensitive Behavior of Supported Vanadia-Based Catalysts for Combustion of Soot

“…Commercial V-based catalysts for SCR reaction also showed great activity in soot oxidation [44,45]. Another application of vanadiumcontaining catalysts in the field of soot combustion is plasma-assisted oxidation [46,47].…”

The Influence of Nonthermal Plasma Technology on Oxidation Characteristics of Soot Operated on Direct Injection Internal Combustion Engines

“…It originates from the accumulation of very small particles of partly burned fuel, partly burned lube oil, ash content of fuel oil, and cylinder lube oil or sulfates and water, posing a significant threat to environmental protection and human health [1][2][3]. Therefore, the catalytic diesel particulate filter (CDPF) has been acclaimed as a potential technique for reducing soot emissions since the presence of catalysts may effectively reduce the ignition temperature of soot and prolong the CDPF's low back pressure [4][5][6]. Creating very effective catalysts for soot oxidation was crucial for CDPF technology.…”